Einkristalldiffraktometer mit CCD-Detektor

• Subject Area: Molecular Chemistry
• Term: Funded in 2011
• Project identifier: Deutsche Forschungsgemeinschaft (DFG) - Project number 196817082

• Final Report Year: 2015

Final Report Abstract

Das Diffraktometer wird für Einkristalle von metallorganischen und organischen Verbindungen eingesetzt, die insbesondere in den Arbeitskreisen Anwander, Bettinger, Kunz, Mayer, Nachtsheim, Schnepf, Sirsch, Wesemann und Ziegler synthetisiert werden. Die Forschungsgebiete liegen im Bereich von neuen Carbenliganden und Metallorganischen Übergangsmetall- und Lanthanoidkomplexen, die teilweise als homogene Katalysatoren (Olefinpolymerisation, Epoxidisomerisierung) dienen sowie von neuen hochreaktiven Zinn-Verbindungen und metalloiden Clustern der 4. Hauptgruppe und binärer subvalenter Halogenide. Insbesondere die Cu-Quelle kommt bei der Vermessung von Einkristallen neuer Carbenliganden, bor- und stickstoffhaltigen cyclischen Verbindungen und Acenderivaten zum Einsatz.

Publications

• A hypervalent iodine-mediated spirocyclization of 2-(4-hydroxybenzamido)acrylates - unexpected formation of δ-spirolactones. Organic & Biomolecular Chemistry, Vol. 10. 2012, pp. 9325-9329.
  Hempel, C., Weckenmann, N. M., Maichle-Mössmer, C., Nachtsheim, B. J.
  
• Anti-[2.2](1,4)pentacenophane: A covalently coupled pentacene dimer. Angewandte Chemie, International, Edition, Vol. 52. 2013, Issue 44, pp. 11647-11650.
  Bula, R., Fingerle, M., Ruff, A., Speiser, B., Maichle-Mössmer, C., Bettinger, H. F.
  
• C-H Functionalization of tetramethylsilane employing a borylnitrene. Chemical Communications, Vol. 49. 2013, pp. 11773-11775.
  Müller, M., Maichle-Mössmer, C., Bettinger, H. F.
  
• Is There B-N Bond Length Alternation in 1,2:3,4:5,6-tris(biphenylylene)borazines? ChemPlusChem, Vol. 78. 2013, Issue 9 (Special Issue: In memory of Detlef Schröder), pp. 988-994.
  Müller, M., Maichle-Mössmer, C., Sirsch, P., Bettinger, H. F.
  
• Rare-Earth-Metal Alkylaluminates Supported by N-Donor-Functionalized Cyclopentadienyl Ligands: CH Bond Activation and Performance in Isoprene Polymerization. Chemistry — A European Journal, Vol. 19. 2013, Issue 48, pp. 16321-16333.
  Jende, L. N., Maichle-Mössmer, C., Anwander, R.
  
• A Dimethylgallium Boryl Complex and Its Methyllithium Addition Compound. Journal of the American Chemical Society, Vol. 136. 2014, Issue 3, pp. 886–889.
  Dettenrieder, N., Schädle, C., Maichle-Mössmer, C., Sirsch, P., Anwander, R.
  
• Assessing the Bronsted Basicity of Diaminoboryl Anions: Reactivity toward Methylated Benzenes and Dihydrogen. Angewandte Chemie, International Edition, Vol. 53. 2014, Issue 24, pp. 6259-6262.
  Dettenrieder, N., Aramaki, Y., Wolf, B. M., Maichle-Mössmer, C., Zhao, X., Yamashita, M., Nozaki, K.. Anwander, R.
  
• Cerium tetrakis(diisopropylamide) - a useful precursor for cerium(IV) chemistry. Chemical Communications, Vol. 50.2014, pp. 14763-14766.
  Schneider, D., Spallek, T., Maichle-Mössmer, C., Törnroos, K. W., Anwander, R.
  
• Divalent Transition Metal Silylamide Ate Complexes. European Journal of Inorganic Chemistry, Vol. 2014, Issue 26, pp. 4302-4309.
  König, S. N., Schneider, D., Maichle-Mössmer, C., Day, B. M., Layfield, R. A., Anwander, R.
  
• Variation of electronic transitions and reduction potentials of cerium(IV) complexes. Dalton Transactions, Vol. 43. 2014, pp. 16197-16206.
  Williams, U. J., Schneider, D., Dorfner, W. L., Maichle-Mössmer, C., Carroll, P. J., Anwander, R., Schelter, E. J.
  
• Evidence for the Formation of Anionic Zerovalent Group 10 Complexes as Highly Reactive Intermediates. Organometallics, Vol. 34. 2015, Issue 12, pp. 2717–2725.
  Seyboldt, A., Wucher, B., Hohnstein, S., Eichele, K., Rominger, F., Törnroos, K. W., Kunz, D.
  
• Rare-Earth-Metal Methyl, Amide, and Imide Complexes Supported by a Superbulky Scorpionate Ligand. Chemistry—A European Journal, Vol. 21. 2015, Issue 2, pp. 662-670.
  Schädle, D., Maichle-Mössmer, C., Schädle, C., Anwander, R.
  
• Reactivity of Yttrium Methyl Complexes: Hydrido Transfer Capability of Selected Alkylalanes. Organometallics, Vol. 34.2015, Issue 11, pp. 2667–2675.
  Schädle, C., Maichle-Mössmer, C., Törnroos, K. W., Anwander, R.
  
• Selective rearrangement of terminal epoxides into methylketones catalysed by a nucleophilic rhodium–NHC–pincer Complex. Chemical Communications, Vol. 51.2015, Issue 10, pp. 1897-1900.
  Jürgens, E., Wucher, B., Rominger, F., Törnroos, K. W., Kunz, D.