Enantiomerenerkennung von chiralen Ethern und Enolethern mit Hilfe der Dirhodiummethode - Selektivität bei der Bindung chiraler polyfunktioneller Carbonylverbindungen

• Applicant: Professor Dr. Helmut Duddeck
• Subject Area: Organic Molecular Chemistry - Synthesis and Characterisation
• Term: from 2005 to 2007
• Project identifier: Deutsche Forschungsgemeinschaft (DFG) - Project number 21768841

• Final Report Year: 2008

Final Report Abstract

No abstract available

Publications

• Enantiodifferentiation of a silane and the analogous hydrocarbon by the dirhodium method – Silane···dirhodium complex interaction, Tetrahedron: Asymm. 17, 1743-1748 (2006)
  E. Díaz Gómez, D. Albert, J. Mattiza, H. Duddeck, J. Chojnowski and M. Cypryk
  
• Enantiodifferentiation of Aliphatic Ethers by the Dirhodium Method, Eur. J. Org. Chem. 2006, 2278-2280
  E. Díaz Gómez, D. Albert, H. Duddeck, S. I. Kozhushkov, A. de Meijere
  
• Adduktbildung von Sauerstoffverbindungen mit dem NMR-Auxiliar Dirhodiumkomplex (Rh*) − Enantiodifferenzierung, Selektivität und Adduktdynamik, Leibniz Universität Hannover, November 2007
  E. Díaz Gómez
  
• Chalcogen Atom Competition in the Coordination of Bicyclic β-Lactam Derivatives to a Dirhodium Tetracarboxylate Complex, Heterocycles 2007, 74, 357-367
  E. Díaz Gómez, J. Frelek, M. Woznica, P. Kowalska, J. Jaźwiński, H. Duddeck
  
• Enantiodifferentiation of Polyethers by the Dirhodium Method – Part 2. Cyclotriveratrylenes and Cryptophanes, Tetrahedron: Asymm. 2007, 18, 2155-2164
  E. Díaz Gómez, T. Brotin, H. Duddeck
  
• Atropisomeric 3-aryl-2-oxo-4-oxazolidinones and some thione analogues – Enantiodifferentiation and ligand competition in applying the dirhodium method, Chirality 2008, 20, 344-350
  E. Díaz Gómez, İ. Doğan, M. Yilmaz, Ö. Demir-Ordu, D. Albert, H. Duddeck
  
• Enantiodifferentiation by 1H NMR Spectroscopy (Dirhodium Method) – Selectivity of Oxygen Functionalities, Nat. Prod. Commun. 2008, 3, 339-344
  E. Díaz Gómez, S. Antus, R. Ferenczi, B. Rys, A. Stankiewicz, H. Duddeck
  
• Origin of 13C Complexation Shifts in the Adduct Formation of 2-Butyl Phenyl Ethers with a Dirhodium Tetracarboxylate Complex, Magn. Reson. Chem. 2008, 46, 23-29
  E. Díaz Gómez and H. Duddeck