CarboTUNE - tuning the electronic structure of functional nanocarbons by means of charge transfer

• Applicant: Professor Dr. Dirk M. Guldi
• Subject Area: Physical Chemistry of Molecules, Liquids and Interfaces, Biophysical Chemistry
• Term: from 2012 to 2016
• Project identifier: Deutsche Forschungsgemeinschaft (DFG) - Project number 226731167

• Final Report Year: 2016

Final Report Abstract

We presented the first comprehensive investigation regarding the covalent attachment of a light harvester / electron donor, that is, a phthalocyanine, to the basal plane of few layer graphene, on one hand, and its full-fledged physico-chemical characterization, on the other hand. Most importantly, the latter included the unambiguous corroboration by means of several steady-state and time-resolved assays of an ultrafast charge separation followed by a slower charge recombination.

Publications

• Linking Photo- and Redoxactive Phthalocyanines Covalently to Graphene. Angew. Chem., 2012, 51, 6421
  M.E. Ragoussi, J. Malig, G. Katsukis, B. Butz, E. Spieker, G. de la Torre, T. Torres, D.M. Guldi
  (See online at https://doi.org/10.1002/anie.201201452)
• Stable Electron Donor-Acceptor Nanohybrids by Interfacing n-Type TCAQ with p-Type Single- Walled Carbon Nanotubes. Angew. Chem., Int. Ed., 2013, 52, 10216
  C. Romero-Nieto, R. Garcia, M.A. Herranz, L. Rodriguez-Perez, M. Sanchez-Navarro, J. Rojo, N. Martin, D.M. Guldi
  (See online at https://doi.org/10.1002/anie.201304032)
• Electron-Accepting Phthalocyanine Pyrene Conjugates: Towards Liquid Phase Exfoliation of Graphite and Photoactive Nanohybrid Formation with Graphene. Chem. Sci., 2014, 5, 3432
  A Roth, M.E. Ragoussi, L. Wibmer, G. Katsukis, G. de la Torre, T. Torres, D.M. Guldi
  (See online at https://doi.org/10.1039/c4sc00709c)
• Electron-donating behavior of few-layer graphene in covalent ensembles with electron-accepting phthalocyanines. J. Am. Chem. Soc., 2014, 136, 4593
  M.-E. Ragoussi, G. Kasukis, A. Roth, J. Malig, G. de la Torre, D.M. Guldi, T. Torres
  (See online at https://doi.org/10.1021/ja411830x)
• Decorating graphene nanosheets with electron accepting pyridyl-phthalocyanines. Nanoscale, 2015, 7, 5674
  L. Wibmer, L.M.O. Lourenco, A. Roth, G. Katsukis, M.G.P.M.S. Neves, J.A.S. Cavaleiro, J.P.C. Tome, T. Torres, D.M. Guldi
  (See online at https://doi.org/10.1039/c4nr05719h)
• Dispersing Perylene Diimide/SWCNT Hybrids: Structural Insights at the Molecular Level and Fabricating Advanced Materials. J. Am. Chem. Soc., 2015, 137, 7429
  Y. Tsarfati, V. Strauss, S. Kuhri, E. Krieg, H. Wiessman, E. Shimoni, J. Baram, D.M. Guldi, B. Rybtchinski
  (See online at https://doi.org/10.1021/jacs.5b03167)