Unified ab initio description of the ultrafast reversible and irreversible laser-induced structural changes occurring in antimony: from coherent phonons up to nonthermal melting
Final Report Abstract
During this project we have studied ultrafast nonequilibrium structural changes in Silicon and Antimony. We have shown that the transient nonequilibrium state generated in Silicon and Antimony by ultrashort intense laser pulses makes ultrafast structural transitions possible, which in thermodynamical equilibrium would become inaccessible. We were able to identify signatures of nonthermal melting which makes it qualitatively different from the well-studied thermal melting. For example, we have demonstrated that the appearance of lattice instabilities and of extreme anisotropic energy-exchange processes is typical for nonthermal phase transitions. Moreover, we performed first principles atomistic simulations on Sb and compared the laser induced ultrafast ionic dynamics with experiments. Our simulations yielded very good agreement with experimentally measured Bragg-peak time evolutions. We succeeded, in collaboration with our experimental partners, in determining the role of coherent and incoherent electron-phonon coupling on the ultrashort dynamics of Sb. Our works served as a basis for further investigations and were published in internationally well-respected journals.
Publications
- Melting of Al induced by laser excitation of 2p holes, Mater. Res. Lett. 3, 149-155 (2015)
Y. Rosandi, F. Cheenicode Kabeer, Y. Cherednikov, E. S. Zijlstra, M. E. Garcia, N. A. Inogamov, and H. M. Urbassek
(See online at https://doi.org/10.1080/21663831.2015.1033564) - Signatures of nonthermal melting, Structural Dynamics 2 , 054101 (2015)
T. Zier , E. S. Zijlstra, A. Kalitsov, I. Theodonis and M. E. Garcia
(See online at https://doi.org/10.1063/1.4928686) - Ab initio molecular dynamics simulations of femtosecond-laser-induced anti-Peierls transition in antimony, Proc. SPIE 9735, 97350K (2016)
E. S. Zijlstra, T. Zier, B. Bauerhenne, S. Krylow, M. E. Garcia
(See online at https://doi.org/10.1117/12.2214668) - Quasimomentum-Space Image for Ultrafast Melting of Silicon, Phys. Rev. Lett. 116, 153901 (2016)
T. Zier, E. S. Zijlstra, M. E. Garcia
(See online at https://doi.org/10.1103/PhysRevLett.116.153901) - Coherent and Incoherent Structual Dynamics in Laser- Excited Antimony, Phys. Rev. B 95, 054302 (2017)
L. Waldecker, Th. Vasileiadis, R. Bertoni, R. Ernstorfer, T. Zier, F. H. Valencia, M. E. Garcia and E. S. Zijlstra
(See online at https://doi.org/10.1103/PhysRevB.95.054302) - Modelling ultrafast laser ablation , J. Phys. D: Appl. Phys. 50, 193001 (2017)
B. Rethfeld, Dmitriy S. Ivanov, M. E. Garcia, and S. I. Anisimov
(See online at https://doi.org/10.1088/1361-6463/50/19/193001) - Molecular dynamics simulations of a femtosecond-laser-induced solid-to-solid transition in antimony, Appl. Phys. A 123, 608 (2017)
B. Bauerhenne, E. S. Zijlstra, M. E. Garcia
(See online at https://doi.org/10.1007/s00339-017-1216-7)
