Controlling the dynamics of active colloidal liquid crystals by external fields
Final Report Abstract
This project focused on the behavior of active colloidal particles, i.e., motile microparticles such as self-propelled microorganisms or microrobots, and the influence of external fields on them. It addressed both the behavior of individual particles as well as the properties of systems of many interacting particles. The latter constitute active materials such as active colloidal liquid crystals. There was a particular focus on sound-propelled microparticles. Active particles with orientation-dependent motility and inertia as well as mixtures of different types of particles were also taken into account. The project developed very well. It led to many new results that went significantly beyond the original objectives of the project. For example, it led to many new results on the fundamental properties of sound-propelled microparticles and to the development of a harmless and medically relevant method that allows to navigate sound-propelled microparticles collectively to a target (e.g., for targeted drug delivery). Other results regarding active-matter systems are the derivation of many new field theories, the observation of new phenomena and effects, a new ansatz for programmable density patterns, a generalized barometric law, and full pair-distribution functions with spatial and orientational degrees of freedom. The project also involved the investigation of active crystals and colloidal liquid crystals, the development of refractive light-propelled microparticles as a new type of artificial active microparticles, and the further development of important methods of statistical physics. Furthermore, the project contributed new results to other fields including hydrodynamics, biophysics, epidemiology, quantum physics, and cosmology. This project resulted in 47 publications, including 4 review articles and 1 patent application. Among the publications are 7 articles published in high-impact journals. The publications are frequently cited and resulted in a large press coverage. The project also led to several awards and further grants.
Publications
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Helical paths, gravitaxis, and separation phenomena for mass-anisotropic self-propelling colloids: Experiment versus theory. The Journal of Chemical Physics, 147(8).
Campbell, Andrew I.; Wittkowski, Raphael; ten Hagen, Borge; Löwen, Hartmut & Ebbens, Stephen J.
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Nonequilibrium dynamics of mixtures of active and passive colloidal particles. New Journal of Physics, 19(10), 105003.
Wittkowski, Raphael; Stenhammar, Joakim & Cates, Michael E.
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Active crystals on a sphere. Physical Review E, 97(5).
Praetorius, Simon; Voigt, Axel; Wittkowski, Raphael & Löwen, Hartmut
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Hydrodynamic resistance matrices of colloidal particles with various shapes.
J. Voß & R. Wittkowski
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Liquid crystals of hard rectangles on flat and cylindrical manifolds. Physical Chemistry Chemical Physics, 20(7), 5285-5294.
Sitta, Christoph E.; Smallenburg, Frank; Wittkowski, Raphael & Löwen, Hartmut
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abp.spherical2d.pairdistribution – Python module that provides a function for the product of the full pair-distribution function and the interparticle force for a homogeneous suspension of spherical active Brownian particles interacting by a Weeks-Chandler-Andersen potential in two spatial dimensions. Accompanying article: J. Jeggle, J. Stenhammar, and R. Wittkowski, Journal of Chemical Physics 152, 194903 (2020).
J. Jeggle; J. Stenhammar & R. Wittkowski
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HydResMat – FEM-based code for calculating the hydrodynamic resistance matrix of an arbitrarily-shaped colloidal particle. Accompanying article: J. Voß and R. Wittkowski
J. Voß; J. Jeggle & R. Wittkowski
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Mori-Zwanzig projection operator formalism for far-from-equilibrium systems with time-dependent Hamiltonians. Physical Review E, 99(6).
te Vrugt, Michael & Wittkowski, Raphael
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Active Brownian Motion with Orientation-Dependent Motility: Theory and Experiments. Langmuir, 36(25), 7066-7073.
Sprenger, Alexander R.; Fernandez-Rodriguez, Miguel Angel; Alvarez, Laura; Isa, Lucio; Wittkowski, Raphael & Löwen, Hartmut
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Classical dynamical density functional theory: from fundamentals to applications. Advances in Physics, 69(2), 121-247.
te Vrugt, Michael; Löwen, Hartmut & Wittkowski, Raphael
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Collective dynamics of active Brownian particles in three spatial dimensions: A predictive field theory. Physical Review Research, 2(3).
Bickmann, Jens & Wittkowski, Raphael
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Effects of social distancing and isolation on epidemic spreading modeled via dynamical density functional theory. Nature Communications, 11(1).
te Vrugt, Michael; Bickmann, Jens & Wittkowski, Raphael
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Eine Fiktion wird Forschungsziel, university newspaper “wissen|leben" no. 7, p. 6, edition November/December (2018)
R. Wittkowski
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On the shape-dependent propulsion of nano- and microparticles by traveling ultrasound waves. Nanoscale Advances, 2(9), 3890-3899.
Voß, Johannes & Wittkowski, Raphael
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Orientational Order Parameters for Arbitrary Quantum Systems. Annalen der Physik, 532(12).
te Vrugt, Michael & Wittkowski, Raphael
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Pair-distribution function of active Brownian spheres in two spatial dimensions: Simulation results and analytic representation. The Journal of Chemical Physics, 152(19).
Jeggle, Julian; Stenhammar, Joakim & Wittkowski, Raphael
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Predictive local field theory for interacting active Brownian spheres in two spatial dimensions. Journal of Physics: Condensed Matter, 32(21), 214001.
Bickmann, Jens & Wittkowski, Raphael
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Projection operators in statistical mechanics: a pedagogical approach. European Journal of Physics, 41(4), 045101.
Vrugt, Michael te & Wittkowski, Raphael
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Relations between angular and Cartesian orientational expansions. AIP Advances, 10(3).
te Vrugt, Michael & Wittkowski, Raphael
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Containing a pandemic: nonpharmaceutical interventions and the ‘second wave’. Journal of Physics Communications, 5(5), 055008.
te Vrugt, Michael; Bickmann, Jens & Wittkowski, Raphael
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Jerky active matter: a phase field crystal model with translational and orientational memory. New Journal of Physics, 23(6), 063023.
te Vrugt, Michael; Jeggle, Julian & Wittkowski, Raphael
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Master equations for Wigner functions with spontaneous collapse and their relation to thermodynamic irreversibility. Journal of Computational Electronics, 20(6), 2209-2231.
te Vrugt, Michael; Tóth, Gyula I. & Wittkowski, Raphael
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Mori-Zwanzig Formalism for General Relativity: A New Approach to the Averaging Problem. Physical Review Letters, 127(23).
te Vrugt, Michael; Hossenfelder, Sabine & Wittkowski, Raphael
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Acoustic Propulsion of Nano- and Microcones: Dependence on the Viscosity of the Surrounding Fluid. Langmuir, 38(35), 10736-10748.
Voß, Johannes & Wittkowski, Raphael
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Acoustically propelled nano- and microcones: fast forward and backward motion. Nanoscale Advances, 4(1), 281-293.
Voß, Johannes & Wittkowski, Raphael
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Analytical approach to chiral active systems: Suppressed phase separation of interacting Brownian circle swimmers. The Journal of Chemical Physics, 156(19).
Bickmann, Jens; Bröker, Stephan; Jeggle, Julian & Wittkowski, Raphael
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ASEVis: Visual Exploration of Active System Ensembles to Define Characteristic Measures. 2022 IEEE Visualization and Visual Analytics (VIS), 150-154.
Evers, Marina; Wittkowski, Raphael & Linsen, Lars
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ASEVis: Visual Exploration of Active System Ensembles to Define Characteristic Measures. 2022 IEEE Visualization and Visual Analytics (VIS), 150-154.
Evers, Marina; Wittkowski, Raphael & Linsen, Lars
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Collective guiding of acoustically propelled nano- and microparticles. Nanoscale Advances, 4(13), 2844-2856.
Nitschke, Tobias; Stenhammar, Joakim & Wittkowski, Raphael
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Derivation and analysis of a phase field crystal model for a mixture of active and passive particles. Modelling and Simulation in Materials Science and Engineering, 30(8), 084001.
Vrugt, Michael te; Holl, Max Philipp; Koch, Aron; Wittkowski, Raphael & Thiele, Uwe
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Orientation-Dependent Propulsion of Triangular Nano- and Microparticles by a Traveling Ultrasound Wave. ACS Nano, 16(3), 3604-3612.
Voß, Johannes & Wittkowski, Raphael
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Perspective: New directions in dynamical density functional theory. Journal of Physics: Condensed Matter, 35(4), 041501.
te Vrugt, Michael & Wittkowski, Raphael
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Pressure Drives Rapid Burst‐Like Coordinated Cellular Motion from 3D Cancer Aggregates. Advanced Science, 9(6).
Raghuraman, Swetha; Schubert, Ann‐Sophie; Bröker, Stephan; Jurado, Alejandro; Müller, Annika; Brandt, Matthias; Vos, Bart E.; Hofemeier, Arne D.; Abbasi, Fatemeh; Stehling, Martin; Wittkowski, Raphael; Ivaska, Johanna & Betz, Timo
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Propulsion of bullet- and cup-shaped nano- and microparticles by traveling ultrasound waves. Physics of Fluids, 34(5).
Voß, Johannes & Wittkowski, Raphael
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Topological fine structure of smectic grain boundaries and tetratic disclination lines within three-dimensional smectic liquid crystals. Physical Chemistry Chemical Physics, 24(26), 15691-15704.
Monderkamp, Paul A.; Wittmann, René; te Vrugt, Michael; Voigt, Axel; Wittkowski, Raphael & Löwen, Hartmut
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abp.ellipsoidal2d.pairdistribution – Python module that provides a function for the full pair-distribution function for a homogeneous suspension of ellipsoidal active Brownian particles interacting by a Gay-Berne potential in two spatial dimensions. Accompanying article: S. Bröker, M. te Vrugt, and R. Wittkowski
S. Bröker; M. te Vrugt & R. Wittkowski
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Acoustic propulsion of nano- and microcones: dependence on particle size, acoustic energy density, and sound frequency.
J. Voß & R. Wittkowski
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Active Brownian particles in external force fields: Field-theoretical models, generalized barometric law, and programmable density patterns. Physical Review E, 108(4).
Bickmann, Jens; Bröker, Stephan; te Vrugt, Michael & Wittkowski, Raphael
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An acoustically controlled helical microrobot. Science Advances, 9(38).
Deng, Yong; Paskert, Adrian; Zhang, Zhiyuan; Wittkowski, Raphael & Ahmed, Daniel
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An active colloidal system showing parallels to a time crystal. Physica Scripta, 98(12), 125240.
Evers, Marina & Wittkowski, Raphael
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Dependence of the acoustic propulsion of nano- and microcones on their orientation and aspect ratio. Scientific Reports, 13(1).
Voß, Johannes & Wittkowski, Raphael
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How to derive a predictive field theory for active Brownian particles: a step-by-step tutorial. Journal of Physics: Condensed Matter, 35(31), 313001.
Vrugt, Michael te; Bickmann, Jens & Wittkowski, Raphael
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Inertial self-propelled particles in anisotropic environments. Communications Physics, 6(1).
Sprenger, Alexander R.; Scholz, Christian; Ldov, Anton; Wittkowski, Raphael & Löwen, Hartmut
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Orientation-Dependent Propulsion of Active Brownian Spheres: From Self-Advection to Programmable Cluster Shapes. Physical Review Letters, 131(16).
Bröker, Stephan; Bickmann, Jens; te Vrugt, Michael; Cates, Michael E. & Wittkowski, Raphael
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Ultrasound-propelled nano- and microspinners.
J. Voß & R. Wittkowski
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Collective dynamics and pair-distribution function of active Brownian ellipsoids in two spatial dimensions. Communications Physics, 7(1).
Bröker, Stephan; te Vrugt, Michael & Wittkowski, Raphael
