Sterically encumbered ligand systems to control of the structure-reactivity relationship in transition metal complexes and to activate small molecules

• Applicant: Professor Dr. Marc D. Walter
• Subject Area: Inorganic Molecular Chemistry - Synthesis and Characterisation
• Term: from 2017 to 2020
• Project identifier: Deutsche Forschungsgemeinschaft (DFG) - Project number 366825329

• Final Report Year: 2020

No abstract available

Publications

• Closing the gap: Preparation and characterization of the first half-open and open manganocene complexes. Organometallics, Vol. 35. 2016, Issue 11, pp. 1986–1994.
  Reiners, Matthias; Baabe, Dirk; Freytag, Matthias; Jones, Peter G. & Walter, Marc D.
  
• Reactivity Studies on [Cp'Fe(μ-I)]2: Nitrido-, Sulfido- and Diselenide Iron Complexes Derived from Pseudohalide Activation. Chemical Science, Vol. 8. 2017, pp. 4108-4122.
  Reiners, Matthias; Maekawa, Miyuki; Daniliuc, Constantin G.; Freytag, Matthias; Jones, Peter G.; White, Peter S.; Hohenberger, Johannes; Sutter, Jörg; Meyer, Karsten; Maron, Laurent & Walter, Marc D.
  
• Synthesis and electronic ground state properties of pyrrolyl-based iron pincer complexes ― revisited. Inorganic Chemistry, Vol. 56. 2017, Issue 14, pp. 8415–8422.
  Ehrlich, Nico; Kreye, Markus; Baabe, Dirk; Schweyen, Peter; Freytag, Matthias; Jones, Peter G. & Walter, Marc D.
  
• [(NHC)CoR2]: Pre-catalysts for homogeneous olefin and alkyne hydrogenation. Chemical Communications, Vol. 54. 2018, pp. 13798-13801.
  Enachi, Andreea; Baabe, Dirk; Zaretzke, Marc-Kevin; Schweyen, Peter; Freytag, Matthias; Raeder, Jan & Walter, Marc D.
  
• Monomeric Fe(III) half-sandwich complexes [Cp'FeX2] - synthesis, properties and electronic structure. Dalton Transactions, Vol. 47.2018, pp. 10517-10526.
  Reiners, Matthias; Maekawa, Miyuki; Baabe, Dirk; Zaretzke, Marc-Kevin; Schweyen, Peter; Daniliuc, Constantin G.; Freytag, Matthias; Raeder, Jan; Hohenberger, Johannes; Sutter, Jörg; Meyer, Karsten & Walter, Marc D.
  
• Pogo-Stick Iron and Cobalt Complexes: Synthesis, Structures and Magnetic Properties. Inorganic Chemistry, Vol. 58. 2019, Issue 24, pp. 16475–16486.
  Peters, Marius; Baabe, Dirk; Maekawa, Miyuki; Bockfeld, Dirk; Zaretzke, Marc-Kevin; Tamm, Matthias & Walter, Marc D.
  
• Enantiomerically Pure Constrained Geometry Complexes of the Rare‐Earth Metals featuring a Dianionic N‐Donor Functionalised Pentadienyl Ligand – Synthesis and Characterisation. Chemistry — European Journal, 2020.
  Münster, Katharina; Fecker, Ann Christin; Raeder, Jan; Freytag, Matthias; Jones, Peter G. & Walter, Marc D.
  
• NH3 formation from N2 and H2 mediated by molecular tri-iron complexes. Nature Chemistry, Vol. 12. 2020, pp. 740–746.
  Reiners, Matthias; Baabe, Dirk; Münster, Katharina; Zaretzke, Marc-Kevin; Freytag, Matthias; Jones, Peter G.; Coppel, Yannick; Bontemps, Sébastien; Rosal, Iker del; Maron, Laurent & Walter, Marc D.