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Artificial Dynamic Guest-Adaptive Hosts for Catalysts and Sensors

Applicant Dr. Zhenpin Lu
Subject Area Organic Molecular Chemistry - Synthesis and Characterisation
Construction Material Sciences, Chemistry, Building Physics
Term from 2017 to 2019
Project identifier Deutsche Forschungsgemeinschaft (DFG) - Project number 372823299
 
Final Report Year 2019

Final Report Abstract

A redox-switchable self-assembled ZnII4L6 cage was synthesized based on naphthalenediimide (NDI) motif. The persistence of the spin-carrying cage was confirmed by cyclic voltammetry experiments and the encapsulation of functionalized C60 supported by NMR titrations. Moreover, this unique cage can act as a supramolecular catalyst for oxidative coupling reactions of borates. The efficiency of the supramolecular catalyst can be dramatically enhanced through the host-guest interaction with C60. Likewise, an FeII4L6 tetrahedral cage was prepared from a redox-active naphthalenediimide (NDI) ligand. This highly charged cage shows a preference for anionic guests with no binding observed for neutral aromatic molecules. When reduced with Cp2Co, the cage releases the anion guests; subsequent oxidation by AgNTf2 led to recovery of the host-guest complexes. Furthermore, the neutral guest fullerene C60 could be encapsulated by the reduced NDI cage. Our results demonstrate the potential to control host-guest interactions using redox stimuli.

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