EXC 236: Tailor-Made Fuels from Biomass
Process Engineering, Technical Chemistry
Final Report Abstract
TMFB was established in 2007 as a new research area at RWTH Aachen on basis of the disciplinary strengths in chemistry, bio- and chemical engineering, and combustion engineering, involving researchers from the Faculty of Natural Sciences, and the Faculty of Mechanical Engineering, together with partners from the Fraunhofer Institute for Molecular Biology and Applied Ecology (Aachen) and the Max Planck Institute für Kohlenforschung (Mühlheim). TMFB’s integrated, interdisciplinary approach defines a unique profile among the rapidly growing number of international activities, which focus either on biomass conversion or on combustion research. Realizing the long-term fundamental scientific challenges of its vision, TMFB’s objectives of the first phase were the establishment of a broad dedicated set of experimental and numerical methods to enable the fuel design process, the generation of high-quality data and information to validate the concepts, and the implementation of scientific and organizational measures to integrate biofuel production and combustion research for the identification of new fuel candidates. The individual results demonstrate convincingly the potential of the interdisciplinary approach, leading to the following conclusions: (1) medium-size oxygen-containing molecules provide promising fuel components, and their molecular diversity can be exploited in a model-assisted fuel design process; (2) novel selective (bio-)chemical transformation processes of lignocellulosic biomass can be developed for the synthesis of such target structures from cellulose and hemicellulose; (3) the combustion of these fuels is nearly free of soot and nitrogen oxide emissions, and the efficiency particularly of spark-ignited combustion can be increased significantly; (4) new methods for conceptual process design and evaluation of alternative production pathways prove the potential for a positive overall energy balance. With the establishment and validation of the new methodologies and the integration of the collaborative network, scientific progress gained full momentum leading to over 550 peer reviewed publications, including collaborative papers in high impact journals. The pioneering role of the Cluster is also confirmed by more than 100 invited keynote and plenary lectures specifically on the TMFB-approach at highly ranked international conferences, and by the International Conference on Fuel Science established by TMFB which attracts over 150 international experts from industry and research institutions each year. Researchers at different stages of their career received highly renowned recognitions and fellowships, including the Alexander-von-Humboldt-Professorship (Matthias Wessling), the Robert-Bosch-Junior Professorship (Regina Palkovits), the Sofia Kovalevskaja Award of the Alexander von Humboldt Foundation (Roberto Rinaldi), and the Wöhler-Award of the German Chemical Society (Leitner, 2009; Schüth, 2011).
Link to the final report
https://doi.org/10.2314/KXP:1742747744
Publications
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(2008): Depolymerization of Cellulose Using Solid Catalysts in Ionic Liquids. In: Angew. Chem. 120 (42), S. 8167–8170
Rinaldi, Roberto; Palkovits, Regina; Schüth, Ferdi
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(2008): Quantum mechanically based estimation of perturbed-chain polar statistical associating fluid theory parameters for analyzing their physical significance and predicting properties. In: The journal of physical chemistry. B 112 (18), S. 5693–5701
van Nhu, Nguyen; Singh, Mahendra; Leonhard, Kai
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(2009): Acid hydrolysis of cellulose as the entry point into biorefinery schemes. In: ChemSusChem 2 (12), S. 1096–1107
Rinaldi, Roberto; Schüth, Ferdi
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(2009): Design of solid catalysts for the conversion of biomass. In: Energy Environ. Sci. 2 (6), S. 610–626
Rinaldi, Roberto; Schüth, Ferdi
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(2009): Investigations of Clustred Diesel Jets under Quiescent High-Pressure and High- Temperature Conditions using Mie, Schlieren and Chemiluminescence Imaging. In: SAE Int. J. Engines 2 (2), S. 272–286
Cárdenas, Maria; Hottenbach, Peter; Kneer, Reinhold; Grünefeld, Gerd
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(2009): Prediction of multicomponent mutual diffusion in liquids: Model discrimination using NMR data. In: Fluid Phase Equilibria 278 (1-2), S. 27–35
Bardow, André; Kriesten, Ernesto; Voda, Mihai Adrian; Casanova, Federico; Blümich, Bernhard; Marquardt, Wolfgang
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Laminar Burning Velocities of Dimethyl Ether, n-Heptane and iso-Octane at High Pressure
Beeckmann, J.; Keppner, J.; Glatz, T.; Peters, N.
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Numerical Investigation of Laminar Burning Velocities of High Octane Fuel Blends Containing Ethanol
Röhl, O.; Jerzembeck, S.; Beeckmann, J.; Peters, N.
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(2010): An integrated catalytic approach to fermentable sugars from cellulose. In: ChemSusChem 3 (10), S. 1151–1153
Rinaldi, Roberto; Engel, Philip; Büchs, Jochen; Spiess, Antje C.; Schüth, Ferdi
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(2010): Charakterisierung von Cellulasepräparationen mittels Streulicht. In: Chemie Ingenieur Technik 82 (1-2), S. 117–120
Spiess, A. C.; Wulfhorst, H.; Jäger, G.; Ellinidou, E.; Büchs, J.
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(2010): Determination of ignition delay times of different hydrocarbons in a new high pressure shock tube. In: Shock Waves 20 (4), S. 307– 316
Heufer, K. A.; Olivier, H.
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(2010): Enzymecatalyzed C–C bond formation using 2-methyltetrahydrofuran (2-MTHF) as (co)solvent: efficient and bio-based alternative to DMSO and MTBE. In: Green Chem. 12 (12), S. 2240
Shanmuganathan, Saravanakumar; Natalia, Dessy; van den Wittenboer, Anne; Kohlmann, Christina; Greiner, Lasse; Domínguez de María, Pablo
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(2010): Hydrogenolysis of cellulose combining mineral acids and hydrogenation catalysts. In: Green Chem. 12 (6), S. 972
Palkovits, Regina; Tajvidi, Kameh; Procelewska, Joanna; Rinaldi, Roberto; Ruppert, Agnieszka
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(2010): Katalytische Umsetzung von Cellobiose. In: Chemie Ingenieur Technik 82 (8), S. 1211–1214
Liauw, M. A.; Winterle, S.
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(2010): Modelling cellulose solubilities in ionic liquids using COSMO-RS. In: Green Chem. 12 (12), S. 2172–2181
Kahlen, Jens; Masuch, Kai; Leonhard, Kai
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(2010): On the mechanism of ruthenium-catalyzed formation of hydrogen from alcohols: a DFT study. In: Chemistry (Weinheim an der Bergstrasse, Germany) 16 (45), S. 13487– 13499
Johansson, Adam Johannes; Zuidema, Erik; Bolm, Carsten
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(2010): Optical and Thermodynamic Investigations of Reference Fuels for Future Combustion Systems. In: SAE Int. J. Fuels Lubr. 3 (2), S. 819–838
Hottenbach, Peter; Brands, Thorsten; Grünefeld, Gerd; Janssen, Andreas; Muether, Martin; Pischinger, Stefan
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(2010): Pentenoic acid pathways for cellulosic biofuels. In: Angewandte Chemie (International ed. in English) 49 (26), S. 4336–4338
Palkovits, Regina
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(2010): Point by point analysis: how ionic liquid affects the enzymatic hydrolysis of native and modified cellulose. In: Green Chem. 12 (11), S. 1959
Engel, Philip; Mladenov, Radoslav; Wulfhorst, Helene; Jäger, Gernot; Spiess, Antje C.
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(2010): Potential of Cellulose-Derived Biofuels for Soot Free Diesel Combustion. In: SAE Int. J. Fuels Lubr. 3 (1), S. 70–84
Janssen, Andreas; Pischinger, Stefan; Muether, Martin
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(2010): Salt-assisted organic-acid-catalyzed depolymerization of cellulose. In: Green Chem. 12 (10), S. 1844
vom Stein, Thorsten; Grande, Philipp; Sibilla, Fabrizio; Commandeur, Ulrich; Fischer, Rainer; Leitner, Walter; Domínguez de María, Pablo
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(2010): Screening of new solvents for artemisininextraction process using ab initio methodology. In: Green Chem. 12 (2), S. 241–251
Lapkin, Alexei A.; Peters, Martina; Greiner, Lasse; Chemat, Smain; Leonhard, Kai; Liauw, Marcel A.; Leitner, Walter
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(2010): Selective and Flexible Transformation of Biomass-Derived Platform Chemicals by a Multifunctional Catalytic System. In: Angew. Chem. 122 (32), S. 5642–5646
Geilen, Frank M. A.; Engendahl, Barthel; Harwardt, Andreas; Marquardt, Wolfgang; Klankermayer, Jürgen; Leitner, Walter
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(2010): Selective hydrogenation of biomass derived substrates using ionic liquid-stabilized ruthenium nanoparticles. In: Green Chem. 12 (9), S. 1634
Julis, Jennifer; Hölscher, Markus; Leitner, Walter
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(2010): The biorenewables opportunity - toward next generation process and product systems. In: AIChE J.
Marquardt, Wolfgang; Harwardt, Andreas; Hechinger, Manuel; Kraemer, Korbinian; Viell, Joern; Voll, Anna
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A Reduced Kinetic Reaction Mechanism for the Autoignition of Dimethyl Ether
Beeckmann, Joachim; Cai, Liming; Röhl, Olaf; Pitsch, Heinz; Peters, Norbert
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(2011): Asymptotic analysis of homogeneous isotropic decaying turbulence with unknown initial conditions. In: Journal of Turbulence 12, N30
Schaefer, P.; Gampert, M.; Goebbert, J. H.; Gauding, M.; Peters, N.
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(2011): Cellulose-based sustainable polymers: state of the art and future trends. In: Macromolecular rapid communications 32 (17), S. 1299–1311
Rose, Marcus; Palkovits, Regina
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(2011): Continuous flow organometallic catalysis: new wind in old sails. In: Chemical communications (Cambridge, England) 47 (13), S. 3691–3701
Hintermair, Ulrich; Franciò, Giancarlo; Leitner, Walter
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(2011): Disintegration and dissolution kinetics of wood chips in ionic liquids. In: Holzforschung 65 (4)
Viell, Jörn; Marquardt, Wolfgang
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(2011): Fick diffusion coefficients of liquid mixtures directly obtained from equilibrium molecular dynamics. In: The journal of physical chemistry. B 115 (44), S. 12921–12929
Liu, Xin; Schnell, Sondre K.; Simon, Jean-Marc; Bedeaux, Dick; Kjelstrup, Signe; Bardow, André; Vlugt, Thijs J. H.
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(2011): From biomass to feedstock: one-step fractionation of lignocellulose components by the selective organic acid-catalyzed depolymerization of hemicellulose in a biphasic system. In: Green Chem. 13 (7), S. 1772–1777
vom Stein, Thorsten; Grande, Philipp M.; Kayser, Henning; Sibilla, Fabrizio; Leitner, Walter; Domínguez de María, Pablo
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(2011): Highly Selective Decarbonylation of 5-(Hydroxymethyl)furfural in the Presence of Compressed Carbon Dioxide. In: Angew. Chem. 123 (30), S. 6963–6966
Geilen, Frank M. A.; vom Stein, Thorsten; Engendahl, Barthel; Winterle, Sonja; Liauw, Marcel A.; Klankermayer, Jürgen; Leitner, Walter
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(2011): Impact Of Physical Properties On Primary Breakup For A Diesel Nozzle Configuration. In: Atomiz Spr 21 (3), S. 221–235
Reddemann, Manuel Armin; Mathieu, F.; Martin, D.; Kneer, R.
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(2011): Nanocompartments with a pH release system based on an engineered OmpF channel protein. In: Soft Matter 7 (2), S. 532–539
Ihle, Saskia; Onaca, Ozana; Rigler, Per; Hauer, Bernhard; Rodríguez-Ropero, Francisco; Fioroni, Marco; Schwaneberg, Ulrich
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(2011): Role of peroxy chemistry in the high-pressure ignition of n-butanol – Experiments and detailed kinetic modelling. In: Combustion and Flame 158 (8), S. 1444–1455
Vranckx, S.; Heufer, K. A.; Lee, C.; Olivier, H.; Schill, L.; Kopp, W. A. et al.
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(2011): Scandium alkyl and amide complexes containing a cyclen-derived (NNNN) macrocyclic ligand: synthesis, structure and ring-opening polymerization activity toward lactide monomers. In: Dalton transactions (Cambridge, England : 2003) 40 (30), S. 7748–7754
Buffet, Jean-Charles; Okuda, Jun
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(2011): Screening of cellulases for biofuel production: online monitoring of the enzymatic hydrolysis of insoluble cellulose using highthroughput scattered light detection. In: Biotechnology journal 6 (1), S. 74–85.
Jäger, Gernot; Wulfhorst, Helene; Zeithammel, Erik U.; Elinidou, Efthimia; Spiess, Antje C.; Büchs, Jochen
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(2011): Selective homogeneous hydrogenation of biogenic carboxylic acids with Ru(TriPhos)H+: a mechanistic study. In: Journal of the American Chemical Society 133 (36), S. 14349–14358
Geilen, Frank M. A.; Engendahl, Barthel; Hölscher, Markus; Klankermayer, Jürgen; Leitner, Walter
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(2011): Separation of butanol from acetone–butanol–ethanol fermentation by a hybrid extraction–distillation process. In: Computers & Chemical Engineering 35 (5), S. 949–963
Kraemer, Korbinian; Harwardt, Andreas; Bronneberg, Rob; Marquardt, Wolfgang
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(2011): Shock tube investigations of ignition delays of n-butanol at elevated pressures between 770 and 1250K. In: Proceedings of the Combustion Institute 33 (1), S. 359–366
Heufer, K. A.; Fernandes, R. X.; Olivier, H.; Beeckmann, J.; Röhl, O.; Peters, N.
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(2011): Tailor-Made Fuels from Biomass for Homogeneous Low-Temperature Diesel Combustion. In: Energy Fuels 25 (10), S. 4734–4744
Janssen, Andreas J.; Kremer, Florian W.; Baron, Jan H.; Muether, Martin; Pischinger, Stefan; Klankermayer, Juergen
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(2011): The allylcalcium monocation: a bridging allyl ligand with a non-bent coordination geometry. In: Angewandte Chemie (International ed. in English) 50 (25), S. 5753– 5756
Lichtenberg, Crispin; Jochmann, Phillip; Spaniol, Thomas P.; Okuda, Jun
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(2011): The secondary splitting of zero-gradient points in a scalar field. In: J Eng Math 71 (1), S. 81–95
Schaefer, P.; Gampert, M.; Gauding, M.; Peters, N.; Treviño, C.
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Numerical Assessment of Emission Sources for a Modified Diesel Engine Running in PCCI Mode on a Mixture of Gasoline and Diesel
Kerschgens, Bruno; Vanegas, Anyelo; Pitsch, Heinz
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(2012): Analysis of the Effect of Bio-Fuels on the Combustion in a Downsized DI SI Engine. In: SAE Int. J. Fuels Lubr. 5 (1), S. 274–288
Thewes, Matthias; Muther, Martin; Brassat, Adrien; Pischinger, Stefan; Sehr, Andreas
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(2012): Biotests for hazard assessment of biofuel fermentation. In: Energy Environ. Sci. 5 (12), S. 9778
Heger, Sebastian; Bluhm, Kerstin; Agler, Matthew T.; Maletz, Sibylle; Schäffer, Andreas; Seiler, Thomas-Benjamin et al.
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(2012): Hydrogenolysis goes bio: from carbohydrates and sugar alcohols to platform chemicals. In: Angewandte Chemie (International ed. in English) 51 (11), S. 2564–2601
Ruppert, Agnieszka M.; Weinberg, Kamil; Palkovits, Regina
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(2012): Reaction network flux analysis: Optimization-based evaluation of reaction pathways for biorenewables processing. In: AIChE J. 58 (6), S. 1788–1801
Voll, A.; Marquardt, W.
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(2012): Solvent-free catalytic depolymerization of cellulose to water-soluble oligosaccharides. In: ChemSusChem 5 (8), S. 1449–1454
Meine, Niklas; Rinaldi, Roberto; Schüth, Ferdi
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(2012): Toxicological and ecotoxicological potencies of biofuels used for the transport sector—a literature review. In: Energy Environ. Sci. 5 (6), S. 7381
Bluhm, Kerstin; Heger, Sebastian; Seiler, Thomas-Benjamin; Hallare, Arnold V.; Schäffer, Andreas; Hollert, Henner
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(2013): An accurate moving boundary formulation in cut-cell methods. In: Journal of Computational Physics 235, S. 786–809
Schneiders, Lennart; Hartmann, Daniel; Meinke, Matthias; Schröder, Wolfgang
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(2013): Carbon Dioxide as a C 1 Building Block for the Formation of Carboxylic Acids by Formal Catalytic Hydrocarboxylation. In: Angew. Chem. 125 (46), S. 12341–12345
Ostapowicz, Thomas G.; Schmitz, Marc; Krystof, Monika; Klankermayer, Jürgen; Leitner, Walter
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(2013): Optimization of Diesel Combustion and Emissions with Tailor-Made Fuels from Biomass. In: SAE Int. J. Fuels Lubr. 6 (3), S. 922–934
Heuser, Benedikt; Kremer, Florian; Pischinger, Stefan; Klankermayer, Jürgen
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(2013): Set of Acidic Resin Catalysts To Correlate Structure and Reactivity in Fructose Conversion to 5-Hydroxymethylfurfural. In: ACS Catal. 3 (2), S. 123–127
Richter, Felix H.; Pupovac, Kristina; Palkovits, Regina; Schüth, Ferdi
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(2013): Transmitted light microscopy for visualizing the turbulent primary breakup of a microscale liquid jet. In: Exp Fluids 54 (11)
Reddemann, Manuel A.; Mathieu, Florian; Kneer, Reinhold
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Optimization of Diesel Combustion and Emissions with Newly Derived Biogenic Alcohols
Heuser, Benedikt; Kremer, Florian; Pischinger, Stefan; Julis, Jennifer; Leitner, Walter
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(2014): Bifunctional nanoparticle–SILP catalysts (NPs@SILP) for the selective deoxygenation of biomass substrates. In: Chemical science 5 (12), S. 4895–4905
Luska, Kylie L.; Julis, Jennifer; Stavitski, Eli; Zakharov, Dmitri N.; Adams, Alina; Leitner, Walter
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(2014): Cellulose and hemicellulose valorisation: an integrated challenge of catalysis and reaction engineering. In: Energy Environ. Sci. 7 (9), S. 2803
Delidovich, I.; Leonhard, K.; Palkovits, R.
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(2014): Platinum-cobalt bimetallic nanoparticles in hollow carbon nanospheres for hydrogenolysis of 5-hydroxymethylfurfural. In: Nature materials 13 (3), S. 293–300
Wang, G. H.; Hilgert, J.; Herrmann Richter, F.; Wang, F.; Bongard, H. J.; Spliethoff, B. et al.
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(2014): Ruthenium-Catalyzed Reductive Methylation of Imines Using Carbon Dioxide and Molecular Hydrogen. In: Angew. Chem. 126 (41), S. 11190– 11194
Beydoun, Kassem; Ghattas, Ghazi; Thenert, Katharina; Klankermayer, Jürgen; Leitner, Walter
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(2014): Time-gated ballistic imaging using a large aperture switching beam. In: Optics express 22 (6), S. 7058–7074
Mathieu, Florian; Reddemann, Manuel A.; Palmer, Johannes; Kneer, Reinhold
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(2015): A Comparison of the Microbial Production and Combustion Characteristics of Three Alcohol Biofuels: Ethanol, 1-Butanol, and 1-Octanol. In: Frontiers in bioengineering and biotechnology 3, S. 112
Kremer, Florian; Blank, Lars M.; Jones, Patrik R.; Akhtar, M. Kalim
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(2015): Automated Discovery of Reaction Pathways, Rate Constants, and Transition States Using Reactive Molecular Dynamics Simulations. In: J. Chem. Theory Comput. 11 (6), S. 2517–2524
Döntgen, Malte; Przybylski-Freund, Marie-Dominique; Kröger, Leif C.; Kopp, Wassja A.; Ismail, Ahmed E.; Leonhard, Kai
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(2015): Basecatalysed cleavage of lignin β-O-4 model compounds in dimethyl carbonate. In: Green Chem. 17 (11), S. 4908–4912
Dabral, Saumya; Mottweiler, Jakob; Rinesch, Torsten; Bolm, Carsten
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(2015): Combustion and emission behavior of linear C8- oxygenates. In: International Journal of Engine Research 16 (5), S. 627–638
Heuser, Benedikt; Mauermann, Peter; Wankhade, Rajendra; Kremer, Florian; Pischinger, Stefan
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(2015): Copper- and Vanadium-Catalyzed Oxidative Cleavage of Lignin using Dioxygen. In: ChemSusChem 8 (12), S. 2106–2113
Mottweiler, Jakob; Puche, Marta; Räuber, Christoph; Schmidt, Thomas; Concepción, Patricia; Corma, Avelino; Bolm, Carsten
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(2015): Hydrogenation of carbon dioxide to methanol using a homogeneous ruthenium-Triphos catalyst: from mechanistic investigations to multiphase catalysis. In: Chemical science 6 (1), S. 693–704
Wesselbaum, Sebastian; Moha, Verena; Meuresch, Markus; Brosinski, Sandra; Thenert, Katharina M.; Kothe, Jens et al.
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(2015): Ignition characteristics of a bio-derived class of saturated and unsaturated furans for engine applications. In: Proceedings of the Combustion Institute 35 (3), S. 2957–2965
Sudholt, Alena; Cai, Liming; Heyne, Joshua; Haas, Francis M.; Pitsch, Heinz; Dryer, Frederick L.
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(2015): Iron-catalysed oxidative cleavage of lignin and β-O-4 lignin model compounds with peroxides in DMSO. In: Green Chem. 17 (11), S. 5001–5008
Mottweiler, Jakob; Rinesch, Torsten; Besson, Claire; Buendia, Julien; Bolm, Carsten
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(2015): Ruthenium- Lignin Model Substrates. In: Angew. Chem. 127 (20), S. 5957–5961
vom Stein, Thorsten; den Hartog, Tim; Buendia, Julien; Stoychev, Spas; Mottweiler, Jakob; Bolm, Carsten et al.
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(2015): Tailor-Made Fuels from Biomass: Potentials of 2- butanone and 2-methylfuran in direct injection spark ignition engines. In: Fuel 167
Hoppe, Fabian; Burke, Ultan; Thewes, Matthias; Heufer, Alexander; Kremer, Florian; Pischinger, Stefan
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(2015): Theoretical Investigation of Intramolecular Hydrogen Shift Reactions in 3-Methyltetrahydrofuran (3-MTHF) Oxidation. In: J. Phys. Chem. A 119 (44), S. 10917–10928
Parab, Prajakta R.; Sakade, Naoki; Sakai, Yasuyuki; Fernandes, Ravi; Heufer, K. Alexander
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(2016): A comprehensive experimental and kinetic modeling study of butanone. In: Combustion and Flame 168, S. 296–309
Burke, Ultan; Beeckmann, Joachim; Kopp, Wassja A.; Uygun, Yasar; Olivier, Herbert; Leonhard, Kai et al.
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(2016): Acute embryo toxicity and teratogenicity of three potential biofuels also used as flavor or solvent. In: The Science of the total environment 566-567, S. 786–795
Bluhm, Kerstin; Seiler, Thomas-Benjamin; Anders, Nico; Klankermayer, Jürgen; Schaeffer, Andreas; Hollert, Henner
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(2016): An efficient conservative cut-cell method for rigid bodies interacting with viscous compressible flows. In: Journal of Computational Physics 311
Schneiders, Lennart; Günther, Claudia; Meinke, Matthias; Schröder, Wolfgang
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(2016): An updated experimental and kinetic modeling study of n-heptane oxidation. In: Combustion and Flame 172
Zhang, Kuiwen; Banyon, Colin; Bugler, John; Curran, H. J.; Rodriguez, Anne; Herbinet, Olivier et al.
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(2016): Can Contemporary Density Functional Theory Predict Energy Spans in Molecular Catalysis Accurately Enough To Be Applicable for in Silico Catalyst Design? A Computational/Experimental Case Study for the Ruthenium-Catalyzed Hydrogenation of Olefins. In: Journal of the American Chemical Society 138 (1), S. 433–443
Rohmann, Kai; Hölscher, Markus; Leitner, Walter
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(2016): Earlystage evaluation of biorefinery processing pathways using process network flux analysis. In: AIChE J. 62 (9), S. 3096–3108
Ulonska, Kirsten; Skiborowski, Mirko; Mitsos, Alexander; Viell, Jörn
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(2016): Genetic and biochemical insights into the itaconate pathway of Ustilago maydis enable enhanced production. In: Metabolic engineering 38, S. 427–435
Geiser, Elena; Przybilla, Sandra K.; Engel, Meike; Kleineberg, Wiebke; Büttner, Linda; Sarikaya, Eda et al.
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(2016): Hydrodynamic instability and shear layer effects in turbulent premixed combustion. In: Physics of Fluids 28
Schlimpert, Stephan; Feldhusen, Antje; Heribert Grimmen, Jerry; Roidl, Benedikt; Meinke, Matthias; Schröder, Wolfgang
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(2016): Ignition characteristics of saturated and unsaturated furans. In: Combustion and Flame 171, S. 133–136
Sudholt, Alena; Lee, Changyoul; Klankermayer, Jürgen; Fernandes, Ravi X.; Pitsch, Heinz
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(2016): Influence of fuel properties on fundamental spray characteristics and soot emissions using different tailor-made fuels from biomass. In: Energy Conversion and Management 108, S. 243–254
Antonio, Garcia; Monsalve-Serrano, Javier; Heuser, Benedikt; Jakob, Markus; Kremer, Florian; Pischinger, Stefan
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(2016): Mechanism-specific and whole-organism ecotoxicity of mono-rhamnolipids. In: The Science of the total environment 548-549, S. 155–163
Johann, Sarah; Seiler, Thomas-Benjamin; Tiso, Till; Bluhm, Kerstin; Blank, Lars M.; Hollert, Henner
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(2016): Nitrogen-Doped Ordered Mesoporous Carbon Supported Bimetallic PtCo Nanoparticles for Upgrading of Biophenolics. In: Angewandte Chemie (International ed. in English) 55 (31), S. 8850–8855
Wang, Guang-Hui; Cao, Zhengwen; Gu, Dong; Pfänder, Norbert; Swertz, Ann- Christin; Spliethoff, Bernd et al.
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(2016): Nonlinear analysis of an acoustically excited laminar premixed flame. In: Combustion and Flame 163, S. 337–357
Schlimpert, Stephan; Meinke, Matthias; Schröder, Wolfgang
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(2016): Ruthenium- Catalyzed Modular Synthesis of Cyclic Tertiary Amines from Lactams. In: Angewandte Chemie (International ed. in English) 55 (41), S. 12841–12844
Westhues, Stefan; Meuresch, Markus; Klankermayer, Jürgen
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(2016): Ruthenium-Catalyzed Synthesis of Dialkoxymethane Ethers Utilizing Carbon Dioxide and Molecular Hydrogen. In: Angew. Chem. 128 (40), S. 12454–12457
Thenert, Katharina; Beydoun, Kassem; Wiesenthal, Jan; Leitner, Walter; Klankermayer, Jürgen
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(2016): Temperature measurements of micro-droplets using pulsed 2-color laser-induced fluorescence with MDR-enhanced energy transfer. In: Experiments in Fluids 57
Palmer, Johannes; Reddemann, Manuel; Kirsch, Valeri; Kneer, Reinhold
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(2016): The Oxidation Potential Number: An Index to Evaluate Inherent Soot Reduction in D.I. Diesel Spray Plumes. In: SAE Int. J. Engines 9 (1), S. 222–236
Graziano, Barbara; Heuser, Benedikt; Kremer, Florian; Pischinger, Stefan; Rohs, Hans
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Computer-Aided Molecular Design by Combining Genetic Algorithms and COSMO-RS 38, S. 115–120
Scheffczyk, Jan; Fleitmann, Lorenz; Schwarz, Annett; Bardow, André; Leonhard, Kai
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(2017): Abnormal combustion phenomena with different fuels in a spark ignition engine with direct fuel injection. In: Combustion and Flame 175, S. 123–137
Pischinger, Stefan; Günther, Marco; Budak, Oguz
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(2017): Advanced Biofuels and Beyond: Chemistry Solutions for Propulsion and Production. In: Angewandte Chemie (International ed. in English) 56 (20), S. 5412–5452
Leitner, Walter; Klankermayer, Jürgen; Pischinger, Stefan; Pitsch, Heinz; Kohse- Höinghaus, Katharina
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(2017): Catalysis Meets Nonthermal Separation for the Production of (Alkyl)phenols and Hydrocarbons from Pyrolysis Oil. In: Angew. Chem. 129 (9), S. 2374–2379
Cao, Zhengwen; Engelhardt, Jan; Dierks, Michael; Clough, Matthew T.; Wang, Guang-Hui; Heracleous, Eleni et al.
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(2017): Cleaner production of cleaner fuels: wind-to-wheel – environmental assessment of CO 2 -based oxymethylene ether as a drop-in fuel. In: Energy & Environmental Science 11 (2), S. 331–343
Deutz, S.; Bongartz, D.; Heuser, B.; Kätelhön, A.; Schulze Langenhorst, L.; Omari, A. et al.
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(2017): Liquid/liquid extraction of biomass-derived lignin from lignocellulosic pretreatments. In: Green Chem. 19 (1), S. 93–97
Stiefel, Serafin; Di Marino, Davide; Eggert, Armin; Kühnrich, Ivo Robert; Schmidt, Markus; Grande, Philipp M. et al.
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(2017): Mechanistic Investigation of the Catalyzed Cleavage for the Lignin β-O-4 Linkage: Implications for Vanillin and Vanillic Acid Formation. In: ACS Sustainable Chem. Eng. 5 (11), S. 9818–9825
Rinesch, Torsten; Mottweiler, Jakob; Puche, Marta; Concepción, Patricia; Corma, Avelino; Bolm, Carsten
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