Photochemically and Magneto Chemically Triggered Storage / Release of Solar Energy in Strained Organic Compounds

• Applicants: Professor Dr. Dirk M. Guldi; Professor Dr. Andreas Hirsch
• Subject Area: Physical Chemistry of Molecules, Liquids and Interfaces, Biophysical Chemistry
• Term: from 2017 to 2021
• Project identifier: Deutsche Forschungsgemeinschaft (DFG) - Project number 391585168

• Final Report Year: 2022

No abstract available

Publications

• Catalytically Triggered Energy Releasefrom Strained Organic Molecules: The Surface Chemistry of Quadricyclane and Norbornadiene opn Pt(111). Chem. Eur. J. 2017, 23, 1613–1622
  Bauer, Udo; Mohr, Susanne; Döpper, Tibor; Bachmann, Philipp; Späth, Florian; Düll, Fabian; Schwarz, Matthias; Brummel, Olaf; Fromm, Lukas; Pinkert, Ute; Görling, Andreas; Hirsch, Andreas; Bachmann, Julien; Steinrück, Hans‐Peter; Libuda, Jörg & Papp, Christian
  
• Anchoring of a Carboxyl-Functionalized Norbornadiene Derivative to an Atomically Defined Cobalt Oxide Surface. J. Phys. Chem. C 2017, 121, 11508–11518
  Schwarz, Matthias; Mohr, Susanne; Xu, Tao; Döpper, Tibor; Weiß, Cornelius; Civale, Katharina; Hirsch, Andreas; Görling, Andreas & Libuda, Jörg
  
• Controlled Catalytic Energy Release of the Norbornadiene/Quadricyclane Molecular Solar Thermal Energy Storage System on Ni(111). J. Phys. Chem. C 2019, 123, 7654–7664
  Bauer, U.; Fromm, L.; Weiß, C.; Bachmann, P.; Späth, F.; Düll, F.; Steinhauer, J.; Hieringer, W.; Görling, A.; Hirsch, A.; Steinrück, H.-P. & Papp, C.
  
• Efficient Cyclization of the Norbornadiene‐Quadricyclane Interconversion Mediated by a Magnetic [Fe3O4−CoSalphen] Nanoparticle Catalyst. ChemPhotoChem 2020, 4, 52–58
  Luchs, Tobias; Lorenz, Patrick & Hirsch, Andreas
  
• Surface chemistry of 2,3-dibromosubstituted norbornadiene/quadricyclane as molecular solar thermal energy storage system on Ni(111). J. Chem. Phys. 2019, 150, 184706
  Bauer, U.; Fromm, L.; Weiß, C.; Späth, F.; Bachmann, P.; Düll, F.; Steinhauer, J.; Matysik, S.; Pominov, A.; Görling, A.; Hirsch, A.; Steinrück, H.-P. & Papp, C.
  
• Photoswitchable Norbornadiene–Quadricyclane Interconversion Mediated by Covalently Linked C60. Chem. A Eur. J. 2020, 26, 5220–5230
  Lorenz, Patrick & Hirsch, Andreas
  
• Molecular Solar Thermal Batteries through Combination of Magnetic Nanoparticle Catalysts and Tailored Norbornadiene Photoswitches. Chem. A Eur. J. 2021, 27, 4993–5002
  Lorenz, Patrick; Luchs, Tobias & Hirsch, Andreas
  
• Solar Energy Storage: Competition between Delocalized Charge Transfer and Localized Excited States in the Norbornadiene to Quadricyclane Photoisomerization. J. Am. Chem. Soc 2022, 144, 153-162
  Alex, Wiebke; Lorenz, Patrick; Henkel, Christian; Clark, Timothy; Hirsch, Andreas & Guldi, Dirk M.
  
• Tunable Photoswitching in Norbornadiene (NBD)/Quadricyclane (QC) – Fullerene Hybrids. Chem. Eur. J. 2021, 27, 14501-14507
  Lorenz, Patrick; Wullschläger, Florian; Rüter, Antonia; Meyer, Bernd & Hirsch, Andreas