The Cooperative Asymmetric Copper Catalysis and Visible-Light Photocatalysis for Sustainable Enantioselective Synthesis

• Applicant: Santosh Pagire, Ph.D.
• Subject Area: Organic Molecular Chemistry - Synthesis and Characterisation
• Term: from 2018 to 2022
• Project identifier: Deutsche Forschungsgemeinschaft (DFG) - Project number 407495001

• Final Report Year: 2022

Final Report Abstract

No abstract available

Publications

• Introduction of a 7-aza-6-MeO-indoline auxiliary in Lewis-acid/photoredox cooperative catalysis: highly enantioselective aminomethylation of α,β-unsaturated amides: Chem. Sci., 2020, 11, 5168-5174
  Pagire, S. K.; Kumagai, N.; Shibasaki, M.
  (See online at https://doi.org/10.1039/d0sc01890b)
• The Different Faces of [Ru(bpy)3Cl2] and fac[Ir(ppy)3] Photocatalysts: Redox Potential Controlled Synthesis of Sulfonylated Fluorenes and Pyrroloindoles from Unactivated Olefins and Sulfonyl Chlorides: Org. Lett. 2020, 22, 7853–7858
  Pagire, S. K.; Kumagai, N.; Shibasaki, M.
  (See online at https://doi.org/10.1021/acs.orglett.0c02760)
• Highly Enantio- and Diastereoselective Synthesis of 1,2,3-Trisubstituted Cyclopropanes from α,β-Unsaturated Amides and Stabilized Sulfur Ylides Catalyzed by a Chiral Copper(I) Complex: ACS Catal. 2021, 11, 11597–11606
  Pagire, S. K.; Kumagai, N.; Shibasaki, M.
  (See online at https://doi.org/10.1021/acscatal.1c02723)