Subvalent aluminum: versatile reagents for the generation of homo- and heterodiatomic Al-E linkages

• Applicant: Professor Dr. Holger Braunschweig
• Subject Area: Inorganic Molecular Chemistry - Synthesis and Characterisation
• Term: from 2020 to 2024
• Project identifier: Deutsche Forschungsgemeinschaft (DFG) - Project number 450280494

• Final Report Year: 2025

No abstract available

Publications

• Cyclo‐Dipnictadialanes. Angewandte Chemie International Edition, 60(45), 24318-24325.
  Nees, Samuel; Fantuzzi, Felipe; Wellnitz, Tim; Fischer, Malte; Siewert, Jan‐Erik; Goettel, James T.; Hofmann, Alexander; Härterich, Marcel; Braunschweig, Holger & Hering‐Junghans, Christian
  
• Isolable Phospha- and Arsaalumenes. Journal of the American Chemical Society, 143(11), 4106-4111.
  Fischer, Malte; Nees, Samuel; Kupfer, Thomas; Goettel, James T.; Braunschweig, Holger & Hering-Junghans, Christian
  
• Stepwise reduction of a base-stabilised ferrocenyl aluminium(iii) dihalide for the synthesis of structurally-diverse dialane species. Chemical Science, 13(33), 9693-9700.
  Dhara, Debabrata; Fantuzzi, Felipe; Härterich, Marcel; Dewhurst, Rian D.; Krummenacher, Ivo; Arrowsmith, Merle; Pranckevicius, Conor & Braunschweig, Holger
  
• On the Reactivity of Phosphaalumenes towards C−C Multiple Bonds. Angewandte Chemie International Edition, 62(10).
  Nees, Samuel; Wellnitz, Tim; Dankert, Fabian; Härterich, Marcel; Dotzauer, Simon; Feldt, Milica; Braunschweig, Holger & Hering‐Junghans, Christian
  
• Trapping of a Transient Base‐Stabilised Alumylene and Alumylene‐Type Reactivity of a Self‐Stabilising Dialumene towards Organic Azides. Chemistry – A European Journal, 29(31).
  Dhara, Debabrata; Jayaraman, Arumugam; Härterich, Marcel; Arrowsmith, Merle; Jürgensen, Malte; Michel, Maximilian & Braunschweig, Holger
  
• A Discrete Trialane with a Near-Linear Al3 Axis. Journal of the American Chemical Society, 146(49), 33536-33542.
  Dhara, Debabrata; Endres, Lukas; Roy, Aritra; Dewhurst, Rian D.; Bertermann, Rüdiger; Fantuzzi, Felipe & Braunschweig, Holger
  
• Synthesis and Reactivity of a Dialane‐Bridged Diradical. Angewandte Chemie International Edition, 63(18).
  Dhara, Debabrata; Endres, Lukas; Krummenacher, Ivo; Arrowsmith, Merle; Dewhurst, Rian D.; Engels, Bernd; Bertermann, Rüdiger; Finze, Maik; Demeshko, Serhiy; Meyer, Franc; Fantuzzi, Felipe & Braunschweig, Holger