Structural and magnetochemical investigations into spin-spin exchange couplings in heteronuclear d-f complexes

• Antragsteller: Professor Dr. Heiko Lueken (†)
• Fachliche Zuordnung: Festkörper- und Oberflächenchemie, Materialsynthese
• Förderung: Förderung von 2002 bis 2010
• Projektkennung: Deutsche Forschungsgemeinschaft (DFG) - Projektnummer 5368662

In the preparative part of the project organometallic europium(II) andgadolinium(III) species will be combined with reactive organometallictransition metal molecules. The former systems comprise di- andtricyclopentadienides, whereas the latter systems consist ofparamagnetic transition metal cyclopentadienyl halides. Theinvestigations are of interest with respect to the exchange pathwaylanthanide--halogen--transition metal. In the theoretical part of the project the computer program formagnetochemical analysis of homodinuclear transition metal andlanthanide compounds will be extended with regard to the heteronuclearsystems under investigation.

• DFG-Verfahren: Schwerpunktprogramme
• Teilprojekt zu: SPP 1137: Molekularer Magnetismus
• Beteiligte Person: Professor Dr. Ullrich Englert