Mechanistic Study of the H2O2-Reactions of FeII-Complexes

• Applicant: Privatdozent Dr. Roland Meier
• Subject Area: Inorganic Molecular Chemistry - Synthesis and Characterisation
• Term: from 2002 to 2009
• Project identifier: Deutsche Forschungsgemeinschaft (DFG) - Project number 5384886

• Final Report Year: 2009

Final Report Abstract

No abstract available

Publications

• Chem. Commun. 2007, 3960-3962. [FeIII(tmdta)]– –twist-boat/half-chair conformer ratio reliably deduced from DFT-calculated Raman spectra
  Meier, R.; Maigut, J.; Kallies, B.; Lehnert, N.; Paulat, F.; Heinemann, F. W.; Zahn, G.; Feth, M. P.; Krautscheid, H.; van Eldik, R.
  
• Inorg. Chem. 2007, 46, 5361-5371. Elucidation of the Solution Structure and Water-Exchange Mechanism of Paramagnetic [FeII(edta)(H2O)]2-
  Maigut, J.; Meier, R.; Zahl, A.; van Eldik, R.
  
• Inorg. Chem. 2008, 47, 5702-5719. Effect of Chelate Dynamics on Water Exchange Reactions of Paramagnetic Aminopolycarboxylate Complexes
  Maigut, J.; Meier, R.; Zahl, A.; van Eldik, R.
  
• Inorg. Chem., 2008, 47, 6314-6321. Influence of Fluoride on the Reversible Binding of NO by [FeII(EDTA)(H2O)]2−. Inhibition of Autoxidation of [FeII(edta)(H2O)]2−
  Maigut, J.; Meier, R.; van Eldik, R.
  
• J. Am. Chem. Soc. 2008, 130, 14556-14569. Triggering Water Exchange Mechanisms via Chelate Architecture. Shielding of Transition Metal Centers by Aminopolycarboxylate Spectator Ligands
  Maigut, J.; Meier, R.; Zahl, A.; van Eldik, R.
  
• Inorg. Chem. 2009, 48, 7864-7884. Detailed Spectroscopic, Thermodynamic, and Kinetic Studies on the Protolytic Equilibria of FeIIIcydta and the Activation of Hydrogen Peroxide
  Brausam, A.; Maigut, J.; Meier, R.; Szilagi, P.; Buschmann, H.-J.; Massa, W.; Homonnay, Z.; van Eldik, R.