Übergangsmetallkomplexe eines vielseitig koordinierenden Heteroborats - Reaktivitätsstudien, Strukturuntersuchungen

• Applicant: Professor Dr. Lars Wesemann
• Subject Area: Inorganic Molecular Chemistry - Synthesis and Characterisation
• Term: from 2004 to 2009
• Project identifier: Deutsche Forschungsgemeinschaft (DFG) - Project number 5443036

• Final Report Year: 2009

Final Report Abstract

No abstract available

Publications

• An unprecedented, reversible coordination mode rearrangement: n3(B-H) vs. n1(Sn) stanna-closo-dodecaborate coordination. Dalton Trans. 2006, 328-329
  T. Gädt, L. Wesemann
  
• Bimetallic Zwitterionic Complexes with an Ambident Stanna-closo-dodecaborate Ligand: [1-{M(CO)5-2,7,8-(µ-H)3-{Fe(triphos)}- SnB11H11] (M = Cr, Mo, W). Organometallics, 2006, 25, 3904-3911
  T. Gädt, K. Eichele, L. Wesemann
  
• Bonding modes of stanna-closo-dodecaborate: n1(Sn) to n3(BH)rearrangement in zwitterionic stannaborate ruthenium complexes. Dalton. Trans. 2006, 2706-2713
  T. Gädt, K. Eichele, L. Wesemann
  
• Ruthenium complexes with the stanna-closo-dodecaborate ligand: coexistence of n1(Sn) and n3(B-H) coordination. Chem. Eur. J. 2006, 12, 1036-1045
  T. Gädt, B. Grau, K. Eichele, I. Pantenburg, L. Wesemann
  
• Iodination of Stanna-closododecaborate. Inorg. Chem. 2007, 46, 2864–2869
  T. Gädt, F. M. Schappacher, R. Pöttgen, L. Wesemann
  
• Stanna-closo-dodecaborate Chemistry. Organometallics, 2007, 26, 2474-2481
  T. Gädt, L. Wesemann
  
• Stanna-closo-dodecaborate: The Crystal Structure of [Li(thf)3]2[SnB11H11], Vibrational Spectroscopy, Thermal Analysis and DFT Calculations Z. anorg. allg. Chem. 2007, 633, 693-699
  T. Gädt, L. Wesemann
  
• Nickel Coordination Compounds of Stanna-closo-dodecaborate Eur. J. Inorg.Chem. 2008, 2261-2265
  M. Kirchmann, T. Gädt, K. Eichele, L. Wesemann
  
• Octahedral Coordination Compounds of the Ni, Pd, Pt Triad Angew. Chem. 2008, 120, 977-980; Angew.Chem. Int Ed. 2008, 47, 963-966
  M. Kirchmann, K. Eichele, F. M. Schappacher, R. Pöttgen, L. Wesemann
  
• Partial Double Bond Character in Chalcogen Compounds of Stannacloso-dodecaborate. Dalton Trans. 2009, 1055-1062
  M. Kirchmann, T. Gädt, F. M. Schappacher, R. Pöttgen, F. Weigend, L. Wesemann