Enantioselektive Gasphasenreaktionen ionischer Übergangsmetallkomplexe

• Applicant: Professor Dr. Helmut Schwarz
• Subject Area: Organic Molecular Chemistry - Synthesis and Characterisation
• Term: from 2004 to 2010
• Project identifier: Deutsche Forschungsgemeinschaft (DFG) - Project number 5444940

• Final Report Year: 2007

Final Report Abstract

No abstract available

Publications

• 'Diastereoselective and enantioselective bond activation of alkanols by gaseous metal ions'. Int. J. Mass Spectrom. 2004, 231, 139
  D. Schröder, H. Schwarz
  
• 'Radical-like activation of alkanes by the ligated copper-oxide cation (phen)CuO+'. J. Phys. Chem. B 2004, 108, 14407
  D. Schröder, M. C. Holthausen, H. Schwarz
  
• 'Competitive reactions and diastereoselective C-H bond activation in the McLafferty rearrangement of photoionized 3-methyl valeramide'. Int. J. Mass Spectrom. 2005, 240, 121
  J. Loos, D. Schröder, H. Schwarz, R. Thissen, O. Dutuit
  
• 'Diastereoselectivity in the McLafferty rearrangement of photoionized 3-methyl valeramide'. J. Org. Chem. 2005, 70, 1073
  J. Loos, D. Schröder, H. Schwarz
  
• 'Fragmentation of catecholato-vanadium(V) alkoxo complexes [(C6H4O2)V(OR1)(OR2)]+ in the gas phase'. Eur. J. Inorg. Chem. 2005, 2919
  M. Kaczorowska, D. Schröder, H. Schwarz
  
• 'Innocent and Less-Innocent Solvent Ligands: A Systematic Investigation of Cationic Iron/Alcohol Complexes by Electrospray Ionization Mass Spectrometry Complemented by DFT Calculations'. Chem. Eur. J. 2006, 12, 2454
  C. Trage, M. Diefenbach, D. Schröder, H. Schwarz
  
• 'Solvent- and ligand effects on the structure of iron-halide cations in the gas phase'. Eur. J. Inorg. Chem. 2006, 4546
  P. Grüne, C. Trage, D. Schröder, H. Schwarz
  
• 'Pronounced Ligand Effects on the Nickel-mediated Thermal Activation of Methane'. Angew. Chem. 2007, 119, 1661; Angew. Chem. Int. Ed. 2007, 46, 1641
  M. Schlangen, D. Schröder, H. Schwarz