Zusammenspiel supramolekularer und makromolekularer Dynamik in transienten Polymernetzwerken

• Antragsteller: Professor Sebastian Seiffert, Ph.D.
• Fachliche Zuordnung: Präparative und Physikalische Chemie von Polymeren
• Förderung: Förderung von 2017 bis 2021
• Projektkennung: Deutsche Forschungsgemeinschaft (DFG) - Projektnummer 376900084

• Erstellungsjahr: 2021

Zusammenfassung der Projektergebnisse

The work of this project has realized the proposed target, despite some changes in the way of how this was done. In addition, several side findings were made and followed. In particular, the project has opened marked further perspectives. Future research will especially focus on the role of sticker clustering in transient networks, which was evidenced to play a decisive enforcing role in our work. This may be suitable for the realization of (hydro)gels with both strong mechanics and reversible and therefore degradable connectivity as cyclic soft materials.

Projektbezogene Publikationen (Auswahl)

• "Enhancement of metallo-supramolecular dissociation kinetics in telechelic terpyridinecapped poly(ethylene glycol) assemblies in the semi-dilute regime." Phys. Chem. Chem. Phys. 2019, 21, 19623–19638
  W. Schmolke, M. Ahmadi, and S. Seiffert
  (Siehe online unter https://doi.org/10.1039/c9cp03911b)
• "Amphiphilic Poly(ether urethanes) Carrying Associative Terpyridine Side Groups with Controlled Spacing." Polymer Chem. 2021, 12, 2305–2316
  K. Breul and S. Seiffert
  (Siehe online unter https://doi.org/10.1039/d1py00121c)
• "Structural and Gelation Characteristics of Metallo-Supramolecular Polymer Model- Network Hydrogels Probed by Static and Dynamic Light Scattering." Macromolecules 2021, 54, 4375–4386
  M. Koziol, K. Fischer, and S. Seiffert
  (Siehe online unter https://doi.org/10.1021/acs.macromol.1c00036)