Umpolung of electrophilic terminal phosphinidene complexes: coordination chemistry to phosphorus and gateway to the chemistry of low-coordinate P-based super-electrophiles

• Applicant: Professor Dr. Rainer Streubel
• Subject Area: Inorganic Molecular Chemistry - Synthesis and Characterisation
• Term: from 2018 to 2023
• Project identifier: Deutsche Forschungsgemeinschaft (DFG) - Project number 404441187

• Final Report Year: 2023

No abstract available

Publications

• A novel access to phosphanylidene–phosphorane complexesviaP-donor substitution and a detailed bonding analysis. Dalton Transactions, 52(38), 13781-13786.
  Biskup, David; Schnakenburg, Gregor; Boeré, René T.; Espinosa, Ferao Arturo & Streubel, Rainer
  
• Challenging an old paradigm by demonstrating transition metal-like chemistry at a neutral nonmetal center. Nature Communications, 14(1).
  Biskup, David; Schnakenburg, Gregor; Boeré, René T.; Espinosa, Ferao Arturo & Streubel, Rainer K.
  
• Nonmetal coordination chemistry: P-adducts of electrophilic, terminal phosphinidene complexes, Rheinische Friedrich-Wilhelms-Universität Bonn, 2023
  David Biskup