Cycloaddition Reactions of Active Cyclic Frustrated Lewis Pairs

• Applicant: Professor Dr. Gerhard Erker
• Subject Area: Organic Molecular Chemistry - Synthesis and Characterisation ; Inorganic Molecular Chemistry - Synthesis and Characterisation
• Term: from 2018 to 2021
• Project identifier: Deutsche Forschungsgemeinschaft (DFG) - Project number 411668360

• Final Report Year: 2021

No abstract available

Publications

• Aggregation Behavior of a Six-Membered Cyclic Frustrated Phosphane/Borane Lewis Pair: Formation of a Supramolecular Cyclooctameric Macrocyclic Ring System, Angew. Chem. Int. Ed. 2019, 58, 882-886
  Jie, Xiaoming; Daniliuc, Constantin G.; Knitsch, Robert; Hansen, Michael Ryan; Eckert, Hellmut; Ehlert, Sebastian; Grimme, Stefan; Kehr, Gerald & Erker, Gerhard
  
• A rare olefin 1,1-carboboration reaction opens a synthetic pathway to an unusually structured frustrated Lewis pair, Chem. Commun. 2020, 56, 8806-8809
  Chen, Chaohuang; Daniliuc, Constantin G.; Mück-Lichtenfeld, Christian; Kehr, Gerald & Erker, Gerhard
  
• Cycloaddition Reactions of an Active Cyclic Phosphane/Borane Pair with Alkenes, Alkynes, and Carbon Dioxide, Chem. Eur. J. 2020, 26, 1269-1273
  Jie, Xiaoming; Sun, Qiu; Daniliuc, Constantin G.; Knitsch, Robert; Hansen, Michael Ryan; Eckert, Hellmut; Kehr, Gerald & Erker, Gerhard
  
• Using the FpXylBH2·SMe2 reagent for the regioselective synthesis of cyclic bis(alkenyl)boranes, Chem. Commun. 2020, 56, 12178-12181
  Škoch, Karel; Daniliuc, Constantin G.; Kehr, Gerald & Erker, Gerhard
  
• Substituent dependent cyclization reactions of 1,1’-bis(alkynyl)ferrocenes with the (C6F5)BH2⋅ SMe2 hydroboration reagent, Eur. J. Inorg. Chem. 2021
  Škoch, Karel; Daniliuc, Constantin G.; Kehr, Gerald & Erker, Gerhard
  
• The Bis(µ6-benzene)lithium Cation: A Fundamental Main-Group Organometallic Species, Angew. Chem. Int. Ed. 2021, 60, 22879-22884
  Jie, Xiaoming; Li, Jun; Daniliuc, Constantin G.; Wübker, Anna‐Lena; Hansen, Michael Ryan; Eckert, Hellmut; Mück‐Lichtenfeld, Christian; Kehr, Gerald & Erker, Gerhard