Untersuchung von Vinylcyclopropan(VCP)-Amide als schnell polymerisierbare, schwundarme und Wasserstoff-Brücken bildende Monomere: Systematische Untersuchung der Synthese und Charakterisierung modular kombinierter Polymernetzwerke

• Antragstellerin: Professorin Dr. Seema Agarwal
• Fachliche Zuordnung: Präparative und Physikalische Chemie von Polymeren
• Förderung: Förderung von 2018 bis 2022
• Projektkennung: Deutsche Forschungsgemeinschaft (DFG) - Projektnummer 416009646

• Erstellungsjahr: 2023

Zusammenfassung der Projektergebnisse

A detailed study was carried out to understand the effect of H-bonding functional units in vinyl cyclopropane (VCP)-derivatives on photopolymerization and the effect on volume shrinkage. Both mono- and bi-functional VCP derivatives were studied for structure-property relationships. A lot of new VCP derivatives were prepared and structurally characterized for achieving the aim. New collaborations with Prof. Gekle’s group at the University of Bayreuth were started validating experimental results with theoretical simulations.

Projektbezogene Publikationen (Auswahl)

• Theoretical and Experimental Study of Monofunctional Vinyl Cyclopropanes Bearing Hydrogen Bond Enabling Side Chains. Macromolecules, 54(1), 11-21.
  Schumacher, Sören; Pantawane, Sanwardhini; Gekle, Stephan & Agarwal, Seema
  
• The Effect of Hydrogen Bonding on Polymerization Behavior of Monofunctional Vinyl Cyclopropane‐Amides with Different Side Chains. Macromolecular Chemistry and Physics, 223(20).
  Schumacher, Sören; Pantawane, Sanwardhini; Gekle, Stephan & Agarwal, Seema