Project Details
Projekt
Cooperative Triazole H-Donors in Asymmetric Dearomatization by Anion-Binding Catalysis (A12#)
Subject Area
Organic Molecular Chemistry - Synthesis and Characterisation
Term
from 2018 to 2021
Project identifier
Deutsche Forschungsgemeinschaft (DFG) - Project number 104405829
In this project, the cooperative binding and reactivity of chiral tetrakis-triazoles (TetraTri) structures as C-H-based neutral anion acceptors in catalytic anion-binding processes will be explored. Thus, the influence and the controllability of self-organized structures, their host-guest complexes (with one or more anions) and the cooperativity nature of the binding will be investigated by physical and analytical methods, complemented by quantum mechanical studies. Finally, novel applications in enantioselective anion-binding organocatalyzed dearomatization process of N- and O-heteroarenes will be developed.
DFG Programme
Collaborative Research Centres
Applicant Institution
Universität Münster
Project Head
Professorin Dr. Olga Garcia Mancheno
