Sterisch abgeschirmte monometallische Lanthanoid-Komplexe (A05)

• Fachliche Zuordnung: Anorganische Molekülchemie - Synthese, Charakterisierung
• Förderung: Förderung seit 2023
• Projektkennung: Deutsche Forschungsgemeinschaft (DFG) - Projektnummer 471424360

The aim of the project is the discovery of formally low-coordinate lanthanide complexes, bearing a bulky carbazole ligand and related ligand systems. The central structural motif will feature a sterically demanding monoanionic carbazolide ligand R to stabilize reactive, relatively low-coordinate complexes. The carbazole framework provides the basis for several interesting properties due to the inherent ability to delocalize charge considerably in the -scaffold. Therefore, both unusual positive and negative charges can be dissipated from the central metal atom and stabilize the resulting reactive complex. The inherently electron-rich ligand can con-tribute to luminescence effects in dependence of coordinated atoms.

• DFG-Verfahren: Sonderforschungsbereiche
• Teilprojekt zu: SFB 1573: 4f for Future
• Antragstellende Institution: Karlsruher Institut für Technologie
• Teilprojektleiter: Dr. Alexander Hinz