Chiral heterometallic complexes for asymmetric synthesis.

• Applicant: Professor Dr. John A. Gladysz
• Subject Area: Organic Molecular Chemistry - Synthesis and Characterisation
• Term: from 2000 to 2007
• Project identifier: Deutsche Forschungsgemeinschaft (DFG) - Project number 5264242

• Final Report Year: 2008

Final Report Abstract

No abstract available

Publications

• "Transition-Metal-Containing Chiral Bidentate Ligands for Enantioselective Catalysis: Non-Metallocene Architectural Units Come of Age". Chem. Commun. 2003, 665-675
  Delacroix, O.; Gladysz, J. A.
  
• 04/99-06/03, "New Concepts for Highly Enantioselective or Active Transition Metal Catalysts: Chiral-at-Rhenium Donor Ligands as Design Elements". Dissertation
  Klemenz Kromm
  
• "A New Cyclometalation Motif: Synthesis, Structure, and Reactivity of Palladacycles that Contain a Chiral Rhenium Fragment in the Backbone and are Catalyst Precursors for Heck Reactions". Organometallics 2005,24,4013-4015
  Friedlein, F. K.; Hampel, F.; Gladysz, J. A.
  
• "Generation and Reactions of Ruthenium Phosphido Complexes (n5-C5H5)RU(PR'3)-(PR2): Remarkably High Phosphorus Basicities and Applications as Ligands for Palladium-Catalyzed Suzuki Cross-Coupling Reactions". Chem. Eur. J. 2005,11, 1402-1416
  Giner Planas, J.; Hampel, F.; Gladysz, J. A.
  
• "Rhenium-Containing Phosphorus Donor Ligands for Palladium-Catalyzed Suzuki Cross-Coupling Reactions; A New Strategy for High-Activity Systems". Organometallics 2005, 24, 245-255
  Eichenseher, S.; Delacroix, O.; Kromm, K.; Hampel, F.; Gladysz, J. A.
  
• "Synthesis and Reactivity of 1,2- and 1,3-Diphosphines that Contain Four Chiral Rhenium Fragments: Architecturally Novel Tetrametallo-DMPE and -DMPP Species that are Unprivileged Ligands for Enantioselective Catalysis". Eur. J. Inorg. Chem. 2005, 2983- 2998
  Kromm, K.; Eichenseher, S.; Prommesberger, M.; Hampel, F.; Gladysz, J. A.
  
• 07/01-03/05, "Rhenium-Containing Phosphines and Phosphine Oxides: New Design Strategies for Highly Active and/or Enantioselective Organometallic Catalysts for Organic Synthesis". Dissertation
  Sandra Eichenseher
  
• "Synthesis, Structure, and Reactivity of Palladacycles that Contain a Chiral Rhenium Fragment in the Backbone: New Cyclometalation and Catalyst Design Strategies". Chem. Eur. J. 2006, 72, 5267-5281
  Friedlein, F. K.; Kromm, K.; Hampel, F.; Gladysz, J. A.
  
• 04/02-03/06, "New Concepts for Enantioselective Organocatalysis and Transition-Metal Catalysis: Chiral-at-Rhenium Donor Ligands as Design Elements". Dissertation
  Florian K. Friedlein