Nucleofugie-Skalen

• Applicant: Professor Dr. Herbert Mayr
• Subject Area: Organic Molecular Chemistry - Synthesis and Characterisation
• Term: from 2003 to 2010
• Project identifier: Deutsche Forschungsgemeinschaft (DFG) - Project number 5403402

• Final Report Year: 2010

Final Report Abstract

No abstract available

Publications

• How Fast Do R-X Bonds Ionize? - A Semiquantitative Approach. Chem. Eur. J. 2006, 12, 1657- 1666
  B. Denegri, A. R. Ofial, S. Juric, A. Streiter, O. Kronja, H. Mayr
  
• Kinetics of the Solvolyses of Benzhydryl Derivatives: Basis for the Construction of a Comprehensive Nucleofugality Scale. Chem. Eur. J. 2006, 12, 1648-1656; Chem. Eur. J. 2006, 12, 5415
  B. Denegri, A. Streiter, S. Juric, A. R. Ofial, O. Kronja, H. Mayr
  
• "Carbokationen-Watching" bei Solvolyse-Reaktionen. Angew. Chem. 2008, 120, 4022-4025; Angew. Chem. Int. Ed. 2008, 47, 3958-3961
  H. F. Schaller, H. Mayr
  
• Direct Observation of the Ionization Step in Solvolysis Reactions: Electrophilicity versus Electrofugality of Carbocations. J. Am. Chem. Soc. 2008, 130, 3012-3022
  H. F. Schaller, A. A. Tishkov, X. Feng, H. Mayr
  
• Can One Predict Changes from SN1 to SN2 Mechanisms? J. Am. Chem. Soc. 2009, 131, 11392-11401
  T. B. Phan, C. Nolte, S. Kobayashi, A. R. Ofial, H. Mayr
  
• How To Predict Changes in Solvolysis Mechanisms. Pure Appl. Chem. 2009, 81,667-683
  H. Mayr, A. R. Ofial
  
• A Practical Guide for Estimating Rates of Heterolysis Reactions. Acc. Chem. Res. 2010
  N. Streidl, B. Denegri, O. Kronja, H. Mayr
  
• Electrophilicity versus Electrofugality of Tritylium Ions in Aqueous Acetonitrile. Chem. Eur. J. 2010, 16, 7478-7487
  M. Horn, H. Mayr
  
• Kinetics of the Solvolyses of Fluoro Substituted Benzhydryl Derivatives: Reference Electrofuges for the Development of a Comprehensive Nucleofugality Scale. Eur. J. Org. Chem. 2010, 1435-1439
  C. Nolte, H. Mayr
  
• Nucleophilicities and Nucleofugalities of Organic Carbonates. Eur. J. Org. Chem. 2010, 4205-4210
  N. Streidl, R. Branzan, H. Mayr
  
• Stabilities of Trityl Protected Substrates: The Wide Mechanistic Spectrum of Trityl Ester Hydrolyses. Chem. Eur. J. 2010, 16, 7469-7477
  M. Horn, H. Mayr