Fast in situ - spectroscopy of electrocatalytic fuel cell reactions - Methodic development and mechanistic studies

• Antragsteller: Professor Dr. Rolf Jürgen Behm
• Fachliche Zuordnung: Physikalische Chemie von Festkörpern und Oberflächen, Materialcharakterisierung
• Förderung: Förderung von 2004 bis 2009
• Projektkennung: Deutsche Forschungsgemeinschaft (DFG) - Projektnummer 5417575

• Erstellungsjahr: 2008

Zusammenfassung der Projektergebnisse

Keine Zusammenfassung vorhanden

Projektbezogene Publikationen (Auswahl)

• Bridge-bonded formate - Active intermediate or spectator Species in formic acid oxidation on a Pt film electrode?, Langmuir, 22 (25), 10399, 2006
  Y.-X. Chen, M. Heinen, Z. Jusys and R.J. Behm
  
• Adsorption and oxidation of ethanol on colloid-based Pt/C, PtRu/C and Pt3Sn/C catalysts: In-situ FTIR spectroscopy and on-line DEMS studies. Chem. Phys. Phys. Chem. 9 (2007) 2686-2696
  Q. Wang, G.Q. Sun, L.H. Jiang, Q. Xin, S.G. Sun, Y.X. Jiang, S.P. Chen, Z. Jusys, and R.J. Behm
  
• CO adsorption kinetics and adlayer build-up studied by combined ATR-FTIR spectroscopy and on-line DEMS under continuous flow conditions, Electrochim. Acta, 53, 1279, 2007
  M. Heinen, Y.-X. Chen, Z. Jusys, and R.J. Behm
  
• In situ ATR-FTIRS coupled with on-line DEMS under controlled mass transport conditions - A novel tool for electrocatalytic reaction studies, Electrochim. Acta, 52, 5634, 2007
  M. Heinen, Y.-X. Chen, Z. Jusys, and R.J. Behm
  
• Kinetic isotope effects in complex reaction networks - An in-situ IR study on formic acid electrooxidation on Pt under controlled mass transport conditions, Chem. Phys. Chem., 8, 380, 2007
  Y.-X. Chen, M. Heinen, Z. Jusys, and R.J. Behm
  
• Potential-Induced COad Island Formation on a Platinum Thin-Film Electrode in the H-upd Potential Region, J. Phys. Chem. C, 111, 435, 2007
  Y.-X. Chen, M. Heinen, Z. Jusys, and R.J. Behm
  
• Room temperature COad desorption/exchange on Pt electrodes -A combined in-situ IR and mass spectrometry study, Chem. Phys. Chem., 8, 2484, 2007
  M. Heinen, Y.-X. Chen, Z. Jusys, and R.J. Behm
  
• Electrooxidation of small organic C2 molecules studied by IRS and combined IRS/DEMS measurements, Ph.D. Thesis, Ulm University (2008)
  Martin Heinen