Untersuchungen der Eignung von Verbindungen mit binären Untereinheiten aus Elementen der Gruppen 14/16 und 15/16 zum Aufbau ternärer oder quaternärer Anionen durch Reaktionen mit Übergangsmetallverbindungen; experimentelle und theoretische Studien zu physikalischen Eigenschaften der Produkte

• Applicant: Professorin Dr. Stefanie Dehnen
• Subject Area: Inorganic Molecular Chemistry - Synthesis and Characterisation
• Term: from 2005 to 2010
• Project identifier: Deutsche Forschungsgemeinschaft (DFG) - Project number 5451160

• Final Report Year: 2009

Final Report Abstract

No abstract available

Publications

• "Efficient Synthesis and Properties of Single Crystalline [SnTe4]4- Salts", Z. Anorg. Allg. Chem. 2006, 632, 1018-1026
  E. Ruzin, A. Kracke, S. Dehnen
  
• "Fine-tuning of optical properties with salts of discrete or polymeric, heterobimetallic telluride anions [M4(µ4-Te)(SnTe4)4]10- (M = Mn, Zn, Cd, Hg) and 3?{[Hg4(µ4-Te)(SnTe4) 3]6- }", Chem. Commun. 2006, 4796-4798
  E. Ruzin, A. Fuchs, S. Dehnen
  
• "Influence of the Counterions on the Structures of Ternary Zn/Sn/Se Anions: Synthesis and Properties of [Rb10(H2O)14.5][Zn4(µ4-Se)(SnSe 4)4] and [Ba5(H2O)32][Zn5Sn(µ3-Se)4(SnSe4)4]", Z. Anorg. Allg. Chem. 2006, 632, 749-755
  E. Ruzin, S. Dehnen
  
• "A coordination chemistry approach towards ternary M/14/16 anions", Coord. Chem. Rev. 2007, 251, 1259-1280
  S. Dehnen, M. Melullis
  
• "Chalcogenido-Bridged Clusters by Reactions of Chalcogenostannate Salts", J. Clust. Sci. 2007, 18, 618-629
  C. Zimmermann, C.E. Anson, S. Dehnen
  
• "Syntheses, Crystal Structures, UV-Vis Spectra and First NMR-Spectra of New Potassium Salts of Chalgogenogermanate Anions", Z. Anorg. Allg. Chem. 2007, 633, 2159-2167
  M. Melullis, S. Dehnen
  
• "Synthesis and Structures of Solvated Tetrasodiumtetrachalcogeno-stannates [Na4(en)4][SnE4] (en = 1,2-diaminoethane; E = Te, Se), and Their Reactions Toward Further Ternary or Quaternary Chalcogenometallates [Mn(en)3]2[Sn2Te 6]·4H2O or [Na10(H2O)34][Mn4(µ4-Se)(SnSe4)4]", Z. Anorg. Allg. Chem. 2007, 633, 820- 829
  E. Ruzin, C. Zimmermann, P. Hillebrecht, S. Dehnen
  
• "Treating [K4(H2O)0.5][SnTe4] with PPh4+ or AsPh4+: Formation of a Highly Air-Stable Tellurostannate Salt, a Tellurolate with One-Coordinate Te Atoms, and a Polytelluride Salt with 1?[Te4(H2O)2]2- Chains", Eur. J. Inorg. Chem. 2007, 4429-4433
  E. Ruzin, W. Massa, S. Dehnen
  
• "One-Size Adjustable-Gap Cluster Anions: Systematic Approach to Multinary, Water Soluble Chalcogenidometallate Compounds", Inorg. Chem. 2008, 47, 5561-5563
  F. Lips, S. Dehnen
  
• "Syntheses, Structures and Reactivity of Novel Hydrates of ortho-Sulfidostannte Salts", Z. Anorg. Allg. Chem. 2008, 634, 995-1001
  E. Ruzin, S. Jakobi, S. Dehnen
  
• "Inorganic Fameworks from [TSe4]4- Anions (T = Ge, Sn): Synthesis, Structures and Ionic Conductivity of {[K2(H2O)3][MnGe4Se10]}n, and {(NMe4)2[MSn4Se10]}n (M = Mn, Fe)", Inorg. Chem. 2009, 48, 1689–1698
  S. Haddadpour, M. Melullis, H. Staesche, C.R. Mariappan, B. Roling, R. Clérac, S. Dehnen
  
• "Synthesis, Structures and Comprehensive NMR-Spectroscopic Investigations of Hetero-Chalcogenidometallates: The Right Mix Toward Multinary Complexes: Structures and NMR- Spectroscopic Data of Hetero-Chalkogenidometallates", Chem. Eur. J. 2009, 15, 5230-5244
  E. Ruzin, E. Zent, E. Matern, W. Massa, S. Dehnen