Untersuchungen zum Reaktionsverhalten von Komplexen mit Metall-Element-Dreifachbindung der Typen (LnM=E) und (LnM=E-M'Lm) (E = Element der 15. Gruppe außer Stickstoff)

• Antragsteller: Professor Dr. Manfred Scheer
• Fachliche Zuordnung: Anorganische Molekülchemie - Synthese, Charakterisierung
• Förderung: Förderung von 2001 bis 2009
• Projektkennung: Deutsche Forschungsgemeinschaft (DFG) - Projektnummer 5340474

• Erstellungsjahr: 2009

Zusammenfassung der Projektergebnisse

Keine Zusammenfassung vorhanden

Projektbezogene Publikationen (Auswahl)

• Complexes with a Metal Phosphorus Triple Bond - A Novel Class of Highly Reactive Compounds 20.12.2001 Singapore (Singapore) Singapore International Chemical Conference II 18. - 20. Dezember 2001
  Manfred Scheer
  
• Complexes with a metal phosphorus triple bond – A novel class of highly reactive compounds Phosphorus, Sulfur, Silicon and Relat. Elem., 2001, 168-169, 179-184
  M. Scheer, P. Kramkowski, M. Schiffer, B. P. Johnson und E. Leiner
  
• Different transformation pathways in the photolysis of [Cp*P{W(CO)5}2] Eur. J. Inorg. Chem., 2001, 1661 - 1663
  M. Schiffer, E. Leiner und M. Scheer
  
• Insertion reactions of nitriles into the P–C bond of [(?1-C5Me5)P{W(CO)5}2] – A novel approach to phosphorus containing heterocycles Angew. Chem., 2001, 113, 3520-3523. Angew. Chem. Int. Ed., 2001, 40, 3413-3416
  M. Schiffer und M. Scheer
  
• Trapping reactions of an intermediate containing a tungsten–phosphorus triple bond with alkynes Chem. Eur. J., 2001, 7, 1855 - 1861
  M. Schiffer und M. Scheer
  
• Complexes with a metal-phosphorus triple bond as versatile building blocks in coordination and organometallic chemistry Phosphorus, Sulfur and Silicon, 2002, 177, 1617 - 1620
  M. Scheer, M. Schiffer, E. Leiner, B. P. Johnson, C. Haindl and S. Umbarkar
  
• Stabilisation of Unstable Moieties by Metalorganic Fragments 9.07.2002 Corfu (Griechenland) 20. International Conference on Metalorganic Chemistry 7. - 12. Juli 2002
  Manfred Scheer
  
• Complexes with a Metal Phosphorus Triple Bond Review: Topics in Current Chemistry 232, New Aspects in Phosphorous Chemistry – Volume IV, 2004, 1 – 23, Springer Verlag, Heidelberg Berlin
  B. P. Johnson, G. Balazs und M. Scheer
  
• Stabilization of unusual Main Group Moieties by Organometallic Fragments 26.7.2004 Vancouver (Kanada) 21. International Conference on Metalorganic Chemistry, 25.-30.7.2004
  Manfred Scheer
  
• Synthesis and reactivity of complexes with an antimony–tungsten and arsenic– tungsten triple bond 27.7.2004 Vancouver (Kanada) 21. International Conference on Metalorganic Chemistry, 25.-30.7.2004
  Manfred Scheer
  
• Antimony-Tungsten Triple Bond – A Stable Complex with a terminal Sb Ligand Angew. Chem. 2005, 117, 4999-5003. Angew. Chem. Int. Ed. 2005, 44, 4920-4924
  G. Balázs, M. Sierka and M. Scheer
  
• Low-coordinate E1 ligand complexes of group 15 elements – A developing area Review: Coord. Chem. Rev. 2006, 250, 1178-1195
  B. P. Johnson, G. Balázs and M. Scheer
  
• Terminally Coordinated AsS and PS Ligands Chem. Eur. J. 2006, 12, 8603-8608
  G. Balázs, J. C. Green and M. Scheer
  
• The surprising and stereoselective formation of P2C10 Cages by reduction of Cp*PCl2 Chem. Commun. 2006, 4542-4544
  O. C. Presly, M. Green, J. C. Jeffery, E. Leiner, M. Murray, C. A. Russell, M. Scheer and U. Vogel
  
• Ring Expansion of a Cp* Moiety – Formation of a 1,2- Diphosphacyclooctatetraene Ligand Angew. Chem. 2007, 119, 4045-4049. Angew. Chem. Int. Ed. 2007, 46, 3971-3975
  M. Scheer, D. Himmel, B. P. Johnson, C. Kuntz and M. Schiffer
  
• Triple Bonds between Transition Metals and the Heavier Elements of Group 14 and 15 Review: Organometallics 2007, 26, 3058-3075
  G. Balázs, L. Gregoriades and M. Scheer
  
• Phosphinidene bridged Metal Complexes as versatile Starting Materials for novel P containing Heterocycles and Cage Compounds 14.7.2008 (Rennes, FR) 23. International Conference on Metalorganic Chemistry, 13.-18.7.2008
  Manfred Scheer
  
• Reactivity of Transition Metal-Phosphorus Triple Bonds towards Triply Bonded [CpMo(CO)2] – Formation of Novel Heteronuclear Cluster Compounds Chem. Eur. J., 2008, 14, 9020 – 9029
  M. Scheer, D. Himmel, Ch. Kuntz, S. Zhan and E. Leiner
  
• 1,2,3-Triphospole derivatives as reactive intermediates Chem. Commun., 2009, 1745 – 1747
  M. Stubenhofer, C. Kuntz, G. Balázs, M. Zabel and M. Scheer
  
• The complexed Triphosphaallyl Radical, Cation and Anion Family Angew. Chem., 2009, 121, 2638 – 2642. Angew. Chem. Int. Ed., 2009, 48, 2600 – 2604
  M. Scheer, Ch. Kuntz, M. Stubenhofer, M. Linseis, R. F. Winter and M. Sierka