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Professor Dr. Martin Oestreich

Address Technische Universität Berlin
Institut für Chemie
Straße des 17. Juni 124
10623 Berlin

Projects

As Applicant
- Current projects
  - Silyl groups as a steering element in enantioconvergent, nickel-catalyzed C(spn)-C(spm) cross-coupling of racemic silylated/germylated electrophiles (Research Grants)
  - Photo-induced radical-ionic bis-functional-group transfer reactions from single, readily available oxime-based surrogates containing a sulfinyl tether (Research Grants)
- Completed projects
  - Asymmetric intramolecular Heck reactions for the construction of quaternary stereocenters - Enantioselective total synthesis of polypyrrolidinoindolin alkaloids. (Emmy Noether International Fellowships)
  - Chiral tetracoordinated silyl anions as novel reagents in stereoselective synthesis (Emmy Noether Independent Junior Research Groups)
  - Dreierlei Strategien zur nichtenzymatischen kinetischen Racematspaltung (Research Grants)
  - Donorvermittelte Gleichgewichtseinstellung diastereomerer Alken-Pd(II)-Zwischenstufen als Schlüsselschritt enantioselektiver C-C-Bindungsknüpfungen (Research Grants)
  - Heterolytische Aktivierung von H-H- und Si-H-Bindungen durch Lewis-Säure-/Lewis-Base-Paare in (asymmetrischen) metallfreien Reduktionen (Research Grants)
  - Regio- und stereoselektive übergangsmetallkatalysierte Knüpfung von Kohlenstoff-Silicium-Bindungen (Research Grants)
  - Zinc Atom Transfer-Based Silylzincation of Alkynes (Research Grants)
  - Kooperative Si-H-Bindungsaktivierung: Erzeugung potenter Siliciumelektrophile für die katalytische C(sp3)-F-Bindungsaktivierung (Research Grants)
  - Erzeugung und Charakterisierung neuartiger übergangsmetallstabilisierter Silyliumionen (Research Grants)
  - Catalytic enantioselective hydrosilylation of pyridines and benzannulated congeners (Research Grants)
  - 3-Silylated Cyclohexa-1,4-dienes as Surrogates for Gaseous and Harmful Hydrosilanes in Lewis-Acid Catalysis (Research Grants)
  - Chiral Sulfur-Stabilized Silicon Cations as Lewis Acids for Enantioselective Diels-Alder Reactions (Research Grants)
  - Enantioselective Silylation of Simple Alcohols by Catalyst-Controlled Dehydrogenative Si-O Coupling (Research Grants)
  - Ionic and Radical Cross-Couplings for Carbon-Silicon Bond Formation (Research Grants)
  - Transition-Metal-Free Transfer Hydrohalogenation (Research Grants)
  - Elucidation of the Reaction Mechanisms of Hydrosilylations with Cationic Transition-Metal Catalysts (Research Grants)
  - Catalytic in-situ generation of functionalized alkali metal reagents and their application in C-C and C-Si bond-forming reactions (Research Grants)
As Participating Researcher
- Current projects
  - EXC 2008: UniSysCat (Clusters of Excellence (ExStra))
- Completed projects
  - GRK 1143: Complex Functional Systems in Chemistry: Design, Development and Applications (International Research Training Groups)
As Project Head
- Completed projects
  - Reversible Stabilization of Silicon-Stereogenic Silylium Ions in Enantioselective Lewis Acid Catalysis (Collaborative Research Centres)

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